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                       314                       Applied Process Design for Chemical and Petrochemical Plants

                                                                      Table 11-3B
                                                         Refrigerant Data and Safety Classifications

                       The following tables replace Tables 1 and 2 of ANSI/ASHRAE 34-1992. The details as to which addendum contained which changes are outlined in
                       the foreword.
                                                                                                          Normal
                       Refrigerant  Chemical                              Chemical       Molecular     Boiling Point a    Safety
                                                                                                     o
                                                                                                                 o
                       Number     Name a,b                                Formula a        Mass a    ( C)        ( F)     Group
                       Methane Series
                       10         tetrachloromethane (carbon tetrachloride)  CCl 4         153.8      77         171       B1
                       11         trichlorofluoromethane                  CCl 3 F          137.4      24          75       A1
                       12         dichlorodifluoromethane                 CCl 2 F 2        120.9      30         22        A1
                       12B1       bromochlorodifluoromethane              CBrClF 2         165.4      4           25
                       12B2       dibromodifluoromethane                  CBr 2 F 2        209.8      25          77
                       13         chlorotrifluoromethane                  CClF 3           104.5      81        115        A1
                       13B1       bromotrifluoromethane                   CBrF 3           148.9      58         72        A1
                       14         tetrafluoromethane (carbon tetrafluoride)  CF 4           88.0     128        198        A1
                       20         trichloromethane (chloroform)           CHCl 3           119.4      61         142
                       21         dichlorofluoromethane                   CHCl 2 F         102.9       9          48       B1
                       22         chlorodifluoromethane                   CHClF 2           86.5      41         41        A1
                       22B1       bromodifluoromethane                    CHBrF 2          130.9      15          5
                       23         trifluoromethane                        CHF 3             70.0      -82       116        A1
                       30         dichloromethane (methylene chloride)    CH 2 Cl 2         84.9      40         104       B2
                       31         chlorofluoromethane                     CH 2 ClF          68.5      -9          16
                       32         difluoromethane (methylene fluoride)    CH 2 F 2          52.0      52         62        A2
                       40         chloromethane (methyl chloride)         CH 3 Cl           50.5      24         12        B2
                       41         fluoromethane (methyl fluoride)         CH 3 F            34.0      78        108
                       50         methane                                 CH 4              16.0     161        259        A3
                       Ethane Series
                       110        hexachloroethane                        CCl 3 CCl 3      236.8     185         365
                       111        pentachlorofluoroethane                 CCl 3 CCl 2 F    220.3     135         275
                       112        1,1,2,2-tetrachloro-1,2-difluoroethane  CCl 2 FCCl 2 F   203.8      93         199
                       112a       1,1,1,2-tetrachloro-2,2-difluoroethane  CCl 3 CClF 2     203.8      91         196
                       113        1,1,2-trichloro-1,2,2-trifluoroethane   CCl 2 FCClF 2    187.4      48         118       A1
                       113a       1,1,1-trichloro-2,2,2-trifluoroethane   CCl 3 CF 3       187.4      46         115
                       114        1,2-dichloro-1,1,2,2-tetrafluoroethane  CClF 2 CClF 2    170.9       4          38       A1
                       114a       1,1-dichloro-1,2,2,2-tetrafluoroethane  CCl 2 FCF 3      170.9       3          37
                       114B2      1,2-dibromo1,1,2,2-tetrafluoroethane    CBrF 2 CBrF 2    259.9      47         117
                       115        chloropentafluoroethane                 CClF 2 CF 3      154.5      39         38        A1
                       116        hexafluoroethane                        CF 3 CF 3        138.0      78        109        A1
                       120        pentachloroethane                       CHCl 2 CCl 3     202.3     162         324
                       123        2,2-dichloro-1,1,1-trifluoroethane      CHCl 2 CF 3      153.0      27          81      B1*
                       123a       1,2-dichloro-1,1,2-trifluoroethane      CHClFCClF 2      153.0      28          82
                       124        2-chloro-1,1,1,2-tetrafluoroethane      CHClFCF 3        136.5      12          10      A1*
                       124a       1-chloro-1,1,2,2-tetrafluoroethane      CClF 2 CHF 2     136.5      10          14
                       125        pentafluoroethane                       CHF 2 CF 3       120.0      49         56       A1*
                       133a       2-chloro-1,1,1-trifluoroethane          CH 2 ClCF 3      118.5       6          43
                       134a       1,1,1,2-tetrafluoroethane               CF 3 CH 2 F      102.0      26         15       A1*
                       140a       1,1,1-trichloroethane (methyl chloroform)  CCl 3 CH 3    133.4      74         165
                       141b       1,1-dichloro-1-fluoroethane             CCl 2 FCH 3      117.0      32          90
                       142b       1-chloro-1,1-difluoroethane             CClF 2 CH 3      100.5      10          14       A2
                       143a       1,1,1-trifluoroethane                   CF 3 CH 3         84.0      47         53        A2
                       150a       1,1-dichloroethane                      CHCl 2 CH 3       99.0      57         135
                       152a       1,1-difluoroethane                      CHF 2 CH 3        66.0      25         13        A2
                       160        chloroethane (ethyl chloride)           CH 3 CH 2 Cl      64.5      12          54
                       170        ethane                                  CH 3 CH 3         30.0      89        128        A3
                       a The chemical name, chemical formula, molecular mass, and normal boiling point are not part of this standard.
                       b The preferred chemical name is followed by the popular name in parentheses.
                       c Unclassified refrigerants indicate either insufficient data to classify or no formal request for classification.
                       d Held open for future use, formerly used as an indicator of the provisional status of safety classifications.
                       e Sublimes.
                       * Indicates removal of provisional status of the classification.
                       (Continued on pages 315 and 316)
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