Page 118 - A Practical Introduction to Optical Mineralogy
P. 118

SILICATE MINERALS                                                            PYROXENE  GROUP
                              51  I                                                            RELIEF  Moderate to high.
                                              !--'""                                        ALTERATION  opx  minerals alter to serpentine as  follows:
                                            /        ~"-...
                              61  I
                                        /v
                                                                                                             3MgSiO,  + 2H2 0--. Mg,(Si 2 0 5 )(0H) 4  + Si0 2
                              71  I
                                       /                   \
                           "'        I                  "" 1\
                           <!)
                           ~  XI  I                                                                 The  serpentine  mineral  is  sometimes  called  bastite.  Orthopyroxenes
                           Oil                                                                      may occasionally alter to amphibole, cummingtonite first being formed:
                           <!)      I             2V"        \
                           ~ 91  I   v
                           <l)                    2V'~
                           Oil                                 1\                                       8(Mg,Fe)Si0,  +  H 2 0--. (Mg,Fe)7Si 8 022(0H) 2  +  (Fe,Mg)O
                           ~  Rl  I   I
                           ;::,.   I  I                          \
                              71                                                                    A rim of amphibole is formed around the opx crystal and iron ores are
                                                                                                    released in  the reaction, often seen in  basic igneous plutonic rocks.
                              1/                                  \   +
                              6(                                                         *BIREFRINGENCE  Low with interference colours from low first order greys (En) to yellow
                               1/                                                                   and reds (iron-rich  members).
                              51  I                                                        INTERFERENCE  Large biaxial figures are seen on sections out at right angles to the (100)
                                                                                               FIG URE
                                                                                                    plane  +ve or -ve (see data above).
                             1.8(  )
                                                                                            *EXTINCTION  All  opx  have  straight  extinction  on  prism  edge  or  main  prismatic
                                                                /                              ANGLE   cleavages.
                             1.78                                                            TWINNING  Absent from  opx.
                                                            /
                             1.76                                /                            *OTHERS  One set of exsolution lamellae is  usually present, parallel to prismatic
                           c                            /
                          .::::                       /     /                                       face  (100).  Another set  may  be present  at  a  high  angle  to  this. The
                          ]   1.74               v      /                                           explanation  has  been given  under the  heading 'Exsolution lamellae' .
                           ~                   n'l   /                                    DISTING UISHING  Orthopyroxenes are distinguished  from  other clinopyroxenes by their
                          0  1.72             ,/                                              FEATU RES   parallel extinction. Opx is length slow whereas andalusite is length fast;
                           ><             /   /   ~                                                  sillimanite, although length slow, has a very small 2V and higher inter-
                          ~  1. 7( I
                                    /  ~                                                    OCCURRENCE  Orthopyroxenes occur in  basic igneous rocks of all types. Mg-rich opx
                           c              v                                                          ference colours.
                             1.68
                               /  /                                                                  occurs  in  ultrabasic  igneous  rocks  such  as  pyroxenites,  harzburgites,
                               v                                                                     Mg spinel. Orthopyroxenes occur in some regional metamorphic rocks,
                             1.66                                                                    lherzolites and picrites, in  association with  Mg olivine, Mg augite and
                             64
                             1. o   10   20   30   40   50   60   70   80   90   100                 particularly charnockites and granulites, and may occur at h!_gh  grades
                                                                                                    during the thermal metamorphism of argillaceous rocks in hornfelses of
                               Mg 2 (Si0 ,),
                                                                                                     the innermost zones of thermal aureoles.
                              e~statite I bronzite  I persthene ~~~;~;sthenel   eulite  I rthoferrosilite
                                           y
                                                                o
                                          h
                        Figure 2.27  Variation  of 2V angle  and  indices  of refraction  in  the  enstatite-
                        orthoferrosilite (orthopyroxene) series.
                  COLO UR  Mg-rich  opx  are  colourless;  Fe-rich  compositions  show  pale  colours
                        from  pale green to pale  brown.
               PLEOCHROISM  Coloured opx show faint pleochroism with a pink to brown, f3 yellow to
                                                   2
                        brown, andy green, due to either Fe +,  Ti or AI  in  the structure.
                   HABIT  Early formed  opx  in i_gneous  rocks appear as  short prismatic crystals.
                *CLEAVAGE  Two  good  prismatic p 10}  cleavages  meet  at  nearly  90°  on  a  basal
                        section.  {  010}  and { 100}  are poor cleavages or partings.
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