Page 118 - Adsorption Technology & Design, Elsevier (1998)
P. 118

114  Processes and cycles


            5.4.4   Rotary beds
            Two  processes  have  been  devised  to  combine  the  advantage  of  the  fixed
            bed in which attrition losses are  small and the moving bed in which the ad-
            sorbent  is more  effectively  utilized.  Both  processes  have  the  adsorbent  in
            a  fixed  position  relative  to  the  wall  of  the  containment  vessel.  In  order
            for the process to operate on a continuous and steady state basis therefore,
            it  is  necessary  both  to  move  the  position  of  the  fixed  bed  relative  to  the
            feed  and  product  lines  and  to  incorporate  a  desorption  or  regeneration
            section.
              Two  types  of  rotary  bed  adsorber  exist.  Both  are  used  for  removing
            and/or  recovering  solvents  from  air  streams.  Figure  5.10 shows  the  rotary
            bed adsorber which comprises a rotating drum containing the adsorbent  in
            several  sections.  It is used  generally for solvent recovery from air streams.
            The  air  enters  the  drum  circumference  to  pass  inwards  through  the
            adsorbent.  Cleaned  air then leaves via a duct which is connected  along the
            drum's  rotational  axis.  One  or  more  of the  adsorbent  sections  is regener-
            ated  by  passing  steam  in  the  reverse  direction  from  the  central  axis  to
            the  circumference  whence  it  leaves  and  passes  to  condensers.  After
            the  regeneration  step  the  adsorbent  is not  cooled  because  the  proportion
            of  the  adsorbent  annulus  which  is  cooling  at  any  one  time  is  relatively
            small  and  the  effect  of a warm  sector  on the  overall efficiency is relatively
            small.
              The  adsorbent wheel shown schematically in Figure 5.11 is used particu-
            larly  for  the  removal  of  volatile  organic  compounds  (VOCs)  from  vent
            streams.  Whether  the  removed  VOCs  can be  recovered  depends  upon  the
            magnitude of the increase  in concentration from the  adsorption step to the
            desorption  step.  Solvent-laden  air  passes  via  a  duct  through  one  side  of
            the  wheel which rotates  slowly. On  the  desorption side a lower flowrate  of
            heated air is used to desorb the VOCs. The two gas ducts do not have to be of
            the same size but it is obvious that the time for desorption must be less than
            or equal to the time for adsorption.


            5.5     FIXED BEDS USED TO SIMULATE MOVING BEDS
            Two basic  approaches  can be  adopted  for  using fixed beds  to simulate  the
            operation  of  moving  beds.  In  the  first,  multiple  fixed  beds  are  used  in
            cascade,  as  shown  in  Figure  5.1.2 (and  described  later  in  Section  7.7.1)  to
            gain most of the benefit of a continuous steady state countercurrent process.
            The  concept is similar to that used in the pulsed bed.  At each switch in the
            cascade  a fully regenerated  bed is added  to the outlet end of a sequence  of
            beds  in series  when  breakthrough  is about  to occur.  At  the  same  time  the
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