Page 1184 - Advanced Organic Chemistry Part A - Structure and Mechanisms, 5th ed (2007) - Carey _ Sundberg

Index

ab initio, see MO Theory of hydrocarbons, computation of, 56–57
absorption bands of nitroalkanes, 591, 597
comparison of a cis-trans isomer pair, 1081 of phosphorus ylides, 600–601
of E- and Z-stilbene, 1087 of representative compounds, table, 593
wavelength ranges for organic acidity functions, 349–350
compounds, 1074 acids, see also carboxylic acids
acenaphthacene strong, gas phase ionization energies, 57
bond lengths of, 751 acrolein, see propenal
acetaldehyde acryloyl lactates
conformation, 148 as dienophiles, 849
hydration, 638 acylases
acetals as catalysts for esterification, 223
conformation, 83, 231–232 acylation
formation of, 640 of alcohols, 664–667
hydrolysis of, 641–645 of amines, 667
general acid catalysis of, 641–644, 669 in Friedel-Crafts reactions, 809–813
nucleophilic catalysis in, 669 acyl halides
solvent isotope effect in, 641 in Friedel-Crafts reactions, 772, 809–813
specific acid catalysis of, 641 Lewis acid complexes of, 810
of salicylic acid relative reactivity of, 328
mechanism of hydrolysis, 668–669 acylium ion
acetic acid derivatives as intermediates
acidity of, 13, 53, 102–103 in alcohol acylation, 666
acetone in Friedel-Crafts acylation, 809–813
aldol reaction of, 685 acyloxy radicals
enolization of, 608 decarboxylation of, 967, 980, 1013
acetophenone acyl radicals
enolization of, 607 addition reactions of, 1032–1033
acetylene, see ethyne decarbonylation of, 967, 1017, 1122
acidity generation of, 1031–1032
of alcohols, 104 from acyl selenides, 1032
of carbonyl compounds, 591–597 from aldehydes, 1031
of carboxylic acids, 13, 53–54, 102–103, 105 SOMO of, 1031
of cyano compounds, 598 stabilization of, 318, 1055
of halogenated alcohols, 105 adamantane
of hydrides of second and third row elements, derivatives, in nucleophilic substitution, 402,
103–104 412–413, 416
1171