Page 125 - Advances in Forensic Applications of Mass Spectrometry - Jehuda Yinon

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Haloperi- J.

Figure 2.13 dol ESI mass spectra for MSD (1100 left) and API 356 (right) observed at adequate fragmentation energy level. (Reprinted from Weinmann W., Sto- ertzel M., Vogt S., and Wendt J., Tune com- pounds for electrospray ionization/in source col- lision-induced dissocia- tion with mass spectra library se

Spectrum from library “Total Library”: Haloperidol LC 1.00e6 eps
20V 517 50V 517 80V 546

461 444 444

400 376 400 376 400
376 358
m/z, amu Spectrum from library “Total Library”: Haloperidol LC 1.00e6 eps 268 m/z, amu Spectrum from library “Total Library”: Haloperidol LC 1.00e6 cps m/z, amu

241 200 206 200
200 165 165
165 123 123
113

80 60 40 % Intensity 20 80 60 40 % Intensity 20 50 % Intensity

4.01e6 110V 4.61e6 190V 3.86e6 230V

400 400 400
376 Mass, amu 376 Mass, amu 376 Mass, amu

Text data from “AGILENT HALO 110” 80 60 40 20 200 0 Text data from “AGILENT HALO 190” 80 60 40 20 165 200 0 Text data from “AGILENT HALO 230” 165 80 123 60 40 20 200 0 © 2004 by CRC Press LLC