Page 321 - Biosystems Engineering
P. 321

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                  4.  Pastes and sludge or caking crystals: Examples are atmospheric
                      and vacuum dryers (agitator dryer).
                  5.  Materials in solution: Examples are atmospheric and vacuum
                      dryers and spray dryers.
                  6.  Special methods: Modern techniques are used, such as infrared
                      dryer, fielectric dryer, greeze dryer, pneumatic dryer, fluid-
                      ized dryer, and the like.

               Drying Conditions
               Drying conditions can be constant or variable. Constant drying con-
               ditions relate to the constancy of temperature, humidity, air velocity,
               method of exposure of the material, and so on.
               Drying Mechanism
               The moisture (or solvent) in wet material occurs in two types, bound
               and unbound moisture. During the drying of material at a specified
               drying condition, the free moisture gets vaporized and reaches an
               equilibrium value. To get a bone-dry material, the temperature has to
               be raised considerably. Such products may absorb equilibrium water
               again as soon as the material is taken out of the oven, however.
                   The rate of the drying curve can show different trends. For some
               materials, the rate is constant throughout. In some cases, there is an
               initial constant-rate period, which is followed by a falling (the point of
               intersection gives critical moisture content) rate. Again, there are a few
               materials for which there are two falling rates (linear and nonlinear).
               When the surface of the material is sufficiently wet, a constant rate of
               drying takes place. When diffusion of liquid from internal pores to the
               surface becomes predominant, heat flows to the insides of the solid
               mass when evaporation and subsequent diffusion take place.
                   The drying rate increases with increasing temperature and veloc-
               ity of air if the slab thickness increases—the drying rate falls off. If the
               air is sufficiently humid, there is a less concentrated gradient, and so
               the drying rate can fall off sharply.
               Internal Mechanism of Liquid Flow
               Internal liquid flow can occur due to the following:
                    1.  Diffusion in continuous homogeneous solids
                    2.  Capillary flow in granular and porous solid
                    3.  Flow caused by shrinkage and pressure gradient
                    4.  Flow caused by gravity
                    5.  Flow caused by the vaporization–condensation process
               Crystallization
               Crystallization is the formation solid particles within a homogeneous
               phase. It may occur as the formation of solid particles in a vapor, as in
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