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Hydrothermal Fluid Circulation and its Effect on Caldera Unrest      399


             where S b is phase saturation (volumetric fraction occupied by phase b), f rock
             porosity and q b a sink or source (if negative) of phase b. Equation (2) is non-linear
             due to the non-linear relations linking phase saturation, capillary pressure and
             relative permeability (Helmig, 1997). If more than one component is present
             (i.e. volcanic gases, such as carbon dioxide or dissolved solid phases), Equation (2) is
                                                                              k
             appropriately modified, expressing the fluid mass per unit volume as r X , where
                                                                              b
                                                                           b
               k
             X represents the mass fraction of component k in phase b. As mentioned above,
               b
             fluid properties that explicitly appear in the mass and energy balance equations may
             change significantly within hydrothermal systems. As a consequence, modelling
             of hydrothermal fluid circulation also requires the definition of appropriate
             equations of state which describe fluid properties at the conditions of interest.
             In some cases it is possible to approximate the behaviour of fluid properties as linear
             function of pressure and temperature. In other cases this is not feasible and more
             accurate non-linear equations of state are required, increasing the complexity of the
             numerical problem.
                The energy balance equation (for phase b) is written assuming local thermal
             equilibrium between solid rock and fluid. It accounts for heat transport by fluid
             convection and by conduction through the porous matrix:
                                                            !
                          @T    X @ðU b r S b Þ    X
                                         b
                                                         b
               ð1   fÞr c R  þ f             þr       u b r h b  þr  fl R rTg  q ¼ 0 (3)
                                                                             E
                      R
                          @t           @t
                                 b                  b
                                           3
             where r R is rock density [kg/m ] (subscript R refers to rock properties); c R is
             specific heat of the rock [J/Kg 1K]; T is temperature [1K]; U b and h b are the internal
             energy and enthalpy of phase b, respectively; l R is rock thermal conductivity [W/
             m1K] (which depends not only on the rock, but also on thermal properties of the
             permeating fluid and on its saturation), and q E represents any energy sink or source
             within the system.
                Due to the difficulty in the simultaneous solution of these highly non-linear
             and fully coupled equations, early models were limited to simple systems (often
             isothermal) with a single-phase fluid of constant properties flowing through a
             homogeneous porous medium (Elder, 1967a, b). Better computational capabilities
             and improved numerical techniques have since allowed solution of the coupled
             energy and mass transport equations. Pioneering studies focused on hydrothermal
             fluid circulation nearby cooling plutons (Cathles, 1977; Norton and Knight, 1977;
             Delaney, 1982), and considered fluid density to be constant everywhere except
             in the evaluation of buoyancy forces (Boussinesq approximation). Subsequent
             improvement in numerical models has been supported by the geothermal industry.
             A detailed overview of geothermal reservoir modelling and its development
             through time is given by Pruess (1990) and O’Sullivan et al. (2001). Modelling of
             heat and fluid flow through porous media is now a well-developed and highly
             sophisticated research field. At present, geothermal simulators include realistic
             descriptions of fluid properties and account for phase transitions and associated
             latent heat effects (Pruess, 1990, 1991; Hayba and Ingebritsen, 1997). Different
             features may characterise specific models, features such as the presence of additional
             fluid components (non-condensable gases or dissolved salt) or sophisticated rock
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