Page 12 - Catalysts for Fine Chemical Synthesis Vol 1 - Robert & Poignant

contents xi

12.8.4 Synthesis of (S,S)-1,1 -bis(a-N,N-
0
dimethylaminophenylmethyl)ferrocene . . . . 206
12.8.5 Synthesis of (aS, a S)-1,1 -bis(a-N,
0
0
N-dimethylaminophenylmethyl)-(R,R)-
1,1 bis(diphenylphosphino)ferrocene . . . . . 207
0
12.8.6 Asymmetric hydrogenation of methyl-(Z)-
3-phenyl-2-methyl-carboxamido-2-propenoate
using (S)-(R)-diamino FERRIPHOS as
chiral ligand . . . . . . . . . . . . . . 209
References . . . . . . . . . . . . . . . . . . . . . 210

13 Employment of Catalysts Working in Tandem . . . . . . . 213
13.1 A one-pot sequential asymmetric hydrogenation
utilizing Rh(I)- and Ru(II)-catalysts
Takayuki Doi and Takashi Takahashi . . . . . . . . 213
13.1.1 Synthesis of ethyl (Z)-4-acetamido-3-oxo-5-
phenyl-4-pentenoate . . . . . . . . . . . 213
13.1.2 Asymmetric hydrogenation of ethyl
4-acetamido-3-oxo-5-phenyl-4-pentenoate . . . 214
References . . . . . . . . . . . . . . . . . . . . . 217

Index . . . . . . . . . . . . . . . . . . . . . . . 219