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602  Dust Explosions in the Process Industries


            from gas explosions would yield an overview of  similarities and discrepancies, which
            would help focus basic research efforts on important areas where dust cloud combustion
            may differ significantlyfrom combustion of premixed gases. Chen, Fan et al. (1996) con-
            ducted turbulent dust and gas explosions in a 12 m long horizontal, one end open tube
            of internal diameter 0.14 m. The gases used were pentane and epoxy propane, and the
            dust was aluminum. Ignition was performed at the closed tube end. Both with the gases
            and the dust, a continuously accelerating flame, headed by a shock wave, was observed
            in the tube. Numerical analysis confirmed that the shock wave was a result of the flame
            acceleration in the tube, caused by the friction between the flowing unburned cloud and
            the tube wall.
              Shi, Zhu, and Radandt (2001) investigated the relationship between chaos theory
            and dust-dispersion-induced turbulence in different test vessels. They found that dust-
            dispersion-inducedturbulence exhibits chaotic features, and they suggested that the use
            of chaos theory in mathematical models of turbulent dust cloud combustion processes
            will  contribute  significantly  to improved description and understanding  of  these
            processes.
              The role of  thermal radiation in the propagation of  turbulent dust flames remains
            partly unresolved. The dust type and particle size are probably important parameters. Gui
            and Cho (1999) investigated the radiant heat transfer in a circulating fluidized bed coal
            combustor and found that the contribution of thermal radiation to the total heat flux was
            in the range 1536%.

            9.2.4.5
            Dust Flames in Closed Vessels

            Constant-volumedust explosionsin closed bombs is another important field of research
            on dust flame propagation. Some work up to  1990 is discussed in Section 4.4.3 in
            Chapter 4 and Sections 7.14 and 7.15 in Chapter 7. Pu et al. (1991) concluded that the
            turbulence structure of experimental dust clouds in the commonly used 20 liter spheri-
            cal dust explosion test bomb had little resemblance to turbulence  structures  in dust
            clouds in accidental dust explosions in industry. Mercer et al. (1998) described a joint
            effort to characterize the turbuZent$ow$eld  inside the 20 liter bomb. Mintz (1995) dis-
            cussed some further problems with 20 liter bomb experiments.
              Wlodarczyk et al. (1993) conductedexperimentsin a 5 liter sphericalexplosionbomb
            to determine the influence of the dust concentration in exploding aluminum dudair
            clouds, on the content of aluminum oxide in the reaction products. Fan, Ding, and Tang
            (1993) developed a dynamic numerical simulation model for the propagation of spher-
            ical Al-dust explosions in closed vessels. Good agreement was found between experi-
            ments and theoretical predictions  for the influence of  particle  size on the pressure
            development in the vessel.
              Dahoe et al. (1995)constructed a 20 liter spherical dust explosion vessel allowing vari-
            ation of the initialpressurebetween atmospheric and 14bar overpressureand initial tem-
            peratures between below 0°C and 250°C. Experiments could also be conducted in
            enriched oxygen atmospheres, up to pure oxygen. The problem of ensuring constanttur-
            bulence of the dust cloud at the moment of ignition, with varying dust concentrationand
            pressure and temperatureof the gas phase, was investigated.Further development of this
            vessel was discussed by Dahoe et al. (1996c), and the reinforced 20 liter vessel was then
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