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Spontaneous imbibition                                       295
















              Figure 10.8 Imbibition oil recovery versus interfacial tension for an Ordos Basin core
              (Wang et al., 2015b).

              permeability and other experimental details, for example, the surfactant
              used, were not reported in their paper. Their conclusion might not univer-
              sally hold as there was only one data point that deviated from the thread of
              the rest of the data points.

              10.5.2 Simulation analysis

              Some surfactants like anionic surfactants can reduce water-oil IFT but may
              not change rock wettability (Sheng, 2013a). Table 10.2 shows the effect of
              IFT reduction by such type of surfactants. The simulation base shale model
              was referred earlier. For the conventional rock, when the IFT is higher than
              0.049 mN/m, oil cannot be recovered by water imbibition without chang-
              ing oil-wetness to water-wetness by surfactant. The capillary number in the
                                               9
              simulation model is in the order of 10 . Such low capillary number cannot
              reduce residual saturations or increase relative permeabilities. Also, such
              intermediate IFT makes the capillary pressure negatively too large so that
              oil cannot flow out of the oil-wet rock.
                 For the case of initially oil-wet shale rock, no matter what values of the
              IFT, no oil can be recovered because of the very low permeability, in addi-
              tion to the reasons mentioned above for the conventional rock. This is a very


              Table 10.2 Oil recovery factors (RF, %) at different IFTs (no wettability alteration).
                                                 Conventional rock   Shale rock
              Permeability, mD                   120                 3.3E-04
              Porosity                           0.24                0.1
              RF at 20 mN/m (initially oil-wet rock)  0              0
              RF at IFT ¼ 0.049 mN/m             0                   0
              RF at IFT ¼ 0.0323 mN/m            20                  0
              RF at IFT ¼ 0.008 mN/m             42                  0
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