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The Impact of Drilling and Production Operations  127


 soiling or chemical deterioration of surfaces. For plants, the impact
 includes damage to chlorophyl and a disruption of photosynthesis. Sulfur
 dioxide can also accumulate in soils, lowering the pH and modifying the
 soil nutrient balance. The impact of air pollutants on humans and animals
 includes irritation and damage to respiratory systems.
   The impact of sulfur dioxide and hydrocarbons (ethene) has been
 observed on plants at concentrations as low as 0.03 ppm and 0.05 ppm,
 respectively. Sulfur dioxide concentrations on the order of 1 ppm can
 cause constriction of airways in the respiratory tracts of humans
 (Seinfeld, 1986).

 3.10 ACOUSTIC IMPACTS


   Some of the operations associated with drilling and production
 can generate high noise (acoustic) levels. The impact of these
 noises, however, is normally small. The most important sources are
 the seismic operations used during exploration. A number of studies
 have been conducted on ways to minimize the environmental impact
 of these operations (Ruiz Soza, 1991; Wren, 1991; Wright, 1991;
 Bertherin, 1991).
   An extensive review of the acoustic impact of drilling and produc-
 tion on marine mammals was conducted by the American Petroleum
 Institute (1989a). This review concluded that acoustic impacts from
 offshore petroleum operations, including sounds from ships, aircraft,
 seismic exploration, drilling, dredging, and production, are limited
 primarily to short-term responses by mammals. For example, an
 airplane flyby can cause pinnipeds (seals and walruses) to jump into
 the water, abandoning their young. No long-term impacts on marine
 mammal populations have been observed, however. Explosives can
 injure mammals in water within a few hundred meters, but seismic
 air guns are not believed to be physically harmful unless the animals
 are very close to the guns.
   The effects of air guns on fish with swim bladders, e.g., anchovies,
 was also studied (American Petroleum Institute, 1987b). The overall
 effects of seismic surveys using air guns appears very small. Notice-
 able effects on eggs and larvae would only result from large numbers
 of multiple exposures to full seismic arrays. The largest reduction in
 survival rate (35%) was for four-day-old larvae exposed 3-4 times to
 air guns passing overhead at a distance of 10 feet. Seismic pulses with
 air guns appear to have a lethal radius for fish of about 1-2 meters.
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