Page 207 - Formation Damage during Improved Oil Recovery Fundamentals and Applications
P. 207

Using Nanofluids to Control Fines Migration in Porous Systems  181


              nanoparticles detachment behaviors during the postflush of the brine
              (Yuan et al., 2017a,c).
                 As nanoparticles pass through porous medium, they are adsorbed and
              strained at the stagnant points on the pore-throat surfaces, which can be
              confirmed by the reduction of effluent-nanoparticle concentrations
              from the injection source (Zhang et al., 2013; Li et al., 2015). The mass-
              balance equation of nanoparticles flowing through permeable media, con-
              sidering their deposition onto rock grains and straining into pore-throats,
              can be written as,
                            @C NP   @C NP   1 @σ NP   1 @S NP
                                 1        1        1         5 0          (4.1)
                             @x D    @t D   φ @t D    φ @t D
                         x
              where, x D 5 ; t D 5  q inj t  .
                         L       φAL
                 Nanoparticles straining rate can be expressed by classical filtration
              kinetics (Gruedes et al., 2006; Massoudieh and Ginn, 2010). Until nano-
              particles adsorption reaches the maximum retention concentration (Yuan,
              2017a), the classic particle-capture kinetics can be applied to quantify the
              transient attachment rates of nanoparticles (Vafai, 2005).

                            @S NP              @σ NP
                                 5 λ s C NP φL;     5 λ ad C NP φL        (4.2)
                             @t D               @t D
                                           h       2     i
                                                  μr  U  2
              when, σ NP , σ NP;max ; σ NP;max1 5 1 2 ð  NP  Þ φð1 2 S or Þ.
                                                2φr P F e;max y
                 During the stage of brine postflush, there are no changes of fluid
              salinity. Hence, it can be concluded that any changes of nanoparticles
              retention concentration are only attributed to the decrease of average
              fluid density, because of the changes of nanoparticle concentrations. The
              average fluid density is expressed as a weighted average of nanoparticles
              and carrier water density:

                       ρ 5 ρ 1 2 C NP Þ 1 ρ NP C NP 5 ρ 1 C NP ρ NP 2 ρ w    (4.3)

                             ð
                                                   w
                            w
                 The maximum retention concentration of nanoparticles becomes a
              function of injected nanoparticles concentration. The detachment of
              nanoparticles occurs instantly along with the abrupt changes of flowing
              nanoparticles concentration. Thus, the mass-balance equation of nanopar-
              ticles during the postflush of brine could be expressed as follows:


                        @C NP         1 σ NP;max1 2 σ NP;max2 @C NP
                              1 1 1                             5 0       (4.4)
                         @x D         φ       C NP         @t D
   202   203   204   205   206   207   208   209   210   211   212