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CHAPTER SIX




              Formation Damage by Organic
              Deposition


              Rouzbeh G. Moghanloo, Davud Davudov and Emmanuel Akita
              The University of Oklahoma, Norman, OK, United States



              Contents
              6.1 Introduction, Definition, Existence State of Asphaltene in Crude Oil, Molecular
                 Structure of Asphaltene, Monitoring, and Remediation       244
                 6.1.1 Introduction                                         244
                 6.1.2 Definition                                           245
                 6.1.3 Molecular structure of asphaltene                    245
                 6.1.4 Monitoring and remediation                           246
                 6.1.5 Experimental techniques to determine asphaltene-onset-pressure and
                      wax-appearance-temperature                            247
              6.2 Asphaltene Formation Mechanisms Review: Precipitation, Aggregation and
                 Deposition Mechanism, Solubility                           247
                 6.2.1 Asphaltene precipitation                             248
                 6.2.2 Solubility parameter                                 249
                 6.2.3 Asphaltene precipitation models                      249
                 6.2.4 Asphaltene deposition                                250
              6.3 Issues With Asphaltene Deposition                         251
                 6.3.1 Asphaltene issues during oil production              251
                 6.3.2 Formation damage and field experience                251
                 6.3.3 Asphaltene deposition during CO 2 flooding           252
              6.4 Deposition in Porous Media                                253
                 6.4.1 Microfluidic experiments                             253
                 6.4.2 Taylor Couette device studies                        254
                 6.4.3 (Imaging) Core flood experiments                     254
                 6.4.4 Porous media studies                                 255
              6.5 Permeability Damage Models                                257
                 6.5.1 Permeability reduction: effect of surface deposition and pore plugging  258
                 6.5.2 Plugging and nonplugging parallel pathways model     258
                 6.5.3 Power law permeability reduction                     260
                 6.5.4 Case studies: evaluation of surface deposition and pore plugging effects  261
                 6.5.5 Effect of flow rate—particle entrainment             268
              6.6 Conclusions                                               269
              References                                                    270
              Further Reading                                               273

              Formation Damage during Improved Oil Recovery.  © 2018 Elsevier Inc.
              DOI: https://doi.org/10.1016/B978-0-12-813782-6.00006-3  All rights reserved.  243
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