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156  7  Simulating Thermal and Chemical Effects of Intruded Magma Solidification Problems

            reviews the development of this subject (Carslaw and Jaeger 1959, Crank 1984,
            Alexiades and Solomon 1993, Zhao and Heinrich 2002). The problem associated
            with numerical modelling of the thermal effect of solidification of intruded magma
            is that the characteristic dimension of the whole geological system under considera-
            tion is on the scale of tens and hundreds of kilometers, but the characteristic dimen-
            sion of the intruded magma, such as a sill or dike (Johnson and Pollard 1973, Lister
            and Kerr 1991, Rubin 1995, Weinberg 1996) is on the scale of meters and tens of
            meters. As a result, the detailed solidification process of the intruded magma might
            not be important, but the thermal effect caused by the heat release during the solidifi-
            cation of the intruded magma is important, at least from the ore body formation and
            mineralization point of view. Since heat release during solidification of the intruded
            magma can be represented by a physically equivalent heat source, it is possible to
            transform the original heat transfer problem with phase change due to solidification
            of the intruded magma into a physically equivalent heat transfer problem without
            phase change but with the equivalent heat source. The above physical understand-
            ing means that from the numerical modelling point of view, we can remove the
            moving boundary problem associated with the detailed solidification process of the
            intruded magma, so that we can use a fixed finite element mesh to consider the ther-
            mal effect of the intruded magma by solving the physically equivalent heat transfer
            problem with an equivalent heat source. This is the basic idea behind the proposed
            equivalent algorithm for simulating the thermal effect of the intruded magma solid-
            ification in this study. The similar, even though not identical, approaches, such as
            the immersed boundary method (Beyer and LeVeque 1992), the level-set method
            (Osher and Sethian 1998, Sethian 1999), the segment projection method (Tornberg
            and Engquist 2003a) and so forth, have been used to tackle other different prob-
            lems with moving interfaces or fronts (Smooke et al. 1999, Mazouchi and Homsy
            2000). In terms of solving partial differential equations with delta function source
            terms numerically, Walden (1999), and Tornberg and Engquist (2003b) have inves-
            tigated the convergence and accuracy of the numerical method. Recently, the fixed
            grid approach has been successfully used to solve the phase change problem associ-
            ated with moisture transport in high-temperature concrete materials (Schrefler 2004,
            Schrefler et al. 2002, Gawin et al. 2003). In this chapter, it will be extended to the
            solution of the phase change problem associated with intruded magma solidification
            in geological systems. The proposed algorithm is only valid when the characteristic
            length scale of the system is much larger than that of the intruded magma, which is
            true for most geological systems (Johnson and Pollard 1973, Lister and Kerr 1991,
            Rubin 1995, Weinberg 1996).
              In what follows, we will present the proposed equivalent algorithm for simulating
            the chemical effect of solidification of the intruded magma in geological systems.
            Since the volatile fluids released during solidification of the intruded magma may
            have many different chemical components/species, it is ideal to describe the gov-
            erning equation of each chemical component separately. However, if the diffusivity
            of each chemical component is assumed to be identical, then the concept of the
            total concentration, which is the summation of the concentration of all the chemical
            components, can be used to describe the governing equation of the released volatile
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