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162 PROCESS AND FORM


              of alkaline-earth cations and strong biological activity
                                                                                       Tropical
              slow down weathering, while promoting the neoforma-                      red earth
              tion or the conservation of clays that are richer in silica. In
                                                                                      Kaolinite
                                                                                           and
              any climate, clay neoformation is more marked in basic                  Kaolinite and
                                                                                      iron
                                                                                         oxides
                                                                                      iron oxides
              volcanic rocks than in acid crystalline rocks.
                                                                                 Losses of silica
                                                                                 Losses  of  silica
                                                                                  and  cations
                                                                                  and cations
                                                          Black cracking
              Topography and drainage                        clay
                                                                            Gains of silica
                                                                            Gains  of  silica
                                                                                cations
                                                                             and
              The effects of local factors mean that a wider range of        and cations
              clay minerals occur in some climatic zones than would  Smectite
                                                              Smectite
              be the case if the climate were the sole determinant of clay
              formation.Take the case of tropical climates. Soils within
              small areas of this climatic zone may contain a range of  Figure 6.5 Clay types in a typical tropical toposequence.
              clay minerals where two distinct leaching regimes sit side  Source: Adapted from Ollier and Pain (1986, 141)
              by side. On sites where high rainfall and good drainage
              promote fast flushing, both cations and silica are removed
              and gibbsite forms. On sites where there is less rapid  of tropical climates. More generally, the extent of chem-
              flushing, but still enough to remove all cations and a little  ical weathering is correlated with the age of continental
              silica, then kaolinite forms. For instance, the type of clay  surfaces (Kronberg and Nesbitt 1981). In regions where
              formed in soils developed in basalts of Hawaii depends  chemical weathering has acted without interruption,
              upon mean annual rainfall, with smectite, kaolinite, and  even if at a variable rate, since the start of the Cenozoic
              bauxite forming a sequence along the gradient of low to  era, advanced and extreme weathering products are com-
              high rainfall.The same is true of clays formed on igneous  monlyfound. Insomeregions,glaciation,volcanism,and
              rocks in California, where the peak contents of different  alluviation have reset the chemical weathering ‘clock’ by
              clay minerals occur in the following order along a mois-  creating fresh rock debris. Soils less than 3 million years
              ture gradient: smectite, illite (only on acid igneous rocks),  old, which display signs of incipient and intermediate
              kaolinite and halloysite, vermiculite, and gibbsite (Singer  weathering, are common in these areas. In view of these
              1980). Similarly, in soils on islands of Indonesia, the clay  complicatingfactors,andthechangesofclimatethathave
              mineral formed depends on the degree of drainage: where  occurred even during the Holocene epoch, claims that
              drainage is good, kaolinite forms; where it is poor, smec-  weathering crusts of recent origin (recent in the sense
              tite forms (Mohr and van Baren 1954; cf. Figure 6.5).  that they are still forming and have been subject to cli-
              This last example serves to show the role played by land-  matic conditions similar to present climatic conditions
              scape position, acting through its influence on drainage,  during their formation) are related to climate must be
              on clay mineral formation. Comparable effects of topog-  looked at guardedly.
              raphy on clay formation in oxisols have been found in
              soils formed on basalt on the central plateau of Brazil
              (Curi and Franzmeier 1984).
                                                        WEATHERING AND HUMANS
              Age
                                                        Limestone weathers faster in urban environments than
              Time is a further factor that obscures the direct climatic  in surrounding rural areas. Archibald Geikie established
              impact on weathering. Ferrallitization, for example,  this fact in his study of the weathering of gravestones in
              results from prolonged leaching. Its association with the  Edinburgh and its environs. Recent studies of weather-
              tropics is partly attributable to the antiquity of many  ing rates on marble gravestones in and around Durham,
              tropical landscapes rather than to the unique properties  England,giveratesof2micronsperyearinaruralsiteand
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