Page 172 - Geology of Carbonate Reservoirs
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DIAGENETIC ENVIRONMENTS AND FACIES  153

               in general more permeable reservoir rocks than limestones with the same porosity.
               There are no unique or universally applicable answers to the questions of how, at
               what rate, and under what controlling circumstances dolomitization occurred, but

               the job of finding and developing dolostone reservoirs is very real. As one is chal-
               lenged to predict the spatial distribution of porosity and permeability in dolomitized
               reservoirs, the questions listed above must be answered. The answers will be found

               only by studying the rocks first - hand. Seismology and wireline logs will offer little
               or no help.
                    Moldic, vuggy, and cavernous pores are formed when carbonate rock matrix and
               pore walls are dissolved when fluids passing through the pore system are undersatu-

               rated with respect to the reservoir rock. These pore types have a common origin
               but they differ greatly in size and shape. The dissolution that affected them may
               occur in shallow -  or deep - burial environments. Molds represent dissolved former
               grains or crystals, vugs represent dissolved spaces larger than the surrounding grains
               or crystals, and caverns include very large dissolution pores. Carlsbad Caverns in
               New Mexico can be thought of as a gigantic pore system. Moldic and vuggy porosity
               may be related to depositional fabric or depositional facies in some cases. Moldic
               pores typically indicate differential solubility between more and less soluble carbon-
               ate constituents in the rock fabric. In some cases, the more soluble constituent may
               be a metastable mineral such as Mg - calcite or aragonite. Preferential dissolution
               may be due to a difference in grain surface area/volume ratio (Walter,  1985 ). Smaller
               grains with large surface area/volume ratio can be dissolved more easily than larger
               ones. Some moldic pores owe their existence to dissolution of large grains within a
               mud matrix after the mud, but not the grains, has undergone replacement or neo-
               morphism to become less soluble. Subsequent exposure to leaching removed the
               soluble grains but the transformed matrix remained intact. Some vugs are simply
               moldic pores that were dissolved to sizes greater than the preexisting grain or crystal
               boundaries.



               6.3  DIAGENETIC ENVIRONMENTS AND FACIES

                 The principal diagenetic environments are the vadose, meteoric phreatic, mixing -
                 zone, marine phreatic, and subsurface or burial environments (Figure  6.4 ). The
               vadose environment lies above the water table and all pores in this domain are fi lled
               with both air and water. Water resides only temporarily in vadose pores, depending
               on the quantity and frequency of precipitation. Water moves through the vadose
               zone leaving only surface - tension films on grain surfaces and meniscus fi lms across


               pore throats. The depth where all pores are filled with water is called the water table.
               That surface represents the top of the phreatic zone. Below that surface, where all

               pores are filled with fresh water, is the meteoric or freshwater phreatic zone. The
               depth to the water table varies depending on subsurface geology, topography, capil-
               larity, and climate. Near the marine environment, fresh water mixes with seawater
               in the mixed phreatic or mixing zone and aquifers saturated with seawater make up
               the marine phreatic environment. Subsurface or burial diagenetic environments are
               those in which water chemistry is unlike either the meteoric or marine phreatic
               zones, and temperature and pressure become increasingly important. Subsurface
               water chemistry is different because it reflects rock – water interactions and water
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