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182                 Chapter 4 - Introduction to Concrete Admixtures


                              Table 11. Strength Gain in Concrete Containing Antifreezing Admixtures

                                Admixture          Amount      % of Strength (28 d) With Respect
                                                                 to Normally Cured Specimens
                                                                     7 d     28 d    90 d

                                Sodium Nitrite       4–6             30      70      90

                                Ca Nitrite + Urea    3–5             35      80     100
                                Ca Chloride          2–3             35      80     100
                                 + Na Chloride




                              REFERENCES



                                1. Ramachandran, V. S.,  Calcium Chloride in Concrete-Science and
                                   Technology, p. 216, Applied Science Publishers, London (1981)
                                2. Collepardi, M., Rossi, G., and Spiga, M. C., Hydration of Tricalcium
                                   Silicate in the Presence of Electrolytes,  Ann. di Chimica, 61:137–148
                                   (1971)
                                3. Tanoutasse, N., The Hydration Mechanism of C A and C S in the Presence
                                                                         3
                                                                                3
                                   of Calcium Chloride and Calcium Sulphate, 5th Int. Symp. Chem. Cements,
                                   Part 2, pp. 372–378, Tokyo (1968)
                                4. Mukherji, K., and Ludwig, U., Influence of Addition of Calcium Chloride
                                   and Calcium Sulphate on the Rate of Hydration of C S and β-C S, Tonind.
                                                                             3        2
                                   Ztg., 97:211–216 (1973)
                                5. Skalny, J., and Maycock, J. N., Mechanisms of Acceleration by Calcium
                                   Chloride—A Review, 77th Annual Meeting, ASTM, Washington, DC,
                                   (June 1974)
                                6. Collepardi, M., and Massida, L., Hydration of Tricalcium Silicate in
                                   Suspension, Ann. di Chimica, 61:160–168 (1971)
                                7. Ramachandran, V. S., Possible States of Chloride in the Hydration of
                                   Tricalcium Silicate in the Presence of Calcium Chloride,  Materiaux et
                                   Constr., 4:3–12 (1971)
                                8. Rio, A., Celani, A., and Saini, A., New Investigation on the Action
                                   Mechanism of Gypsum and Calcium Chloride and Their Influence on the
                                   Structural and Mechanical Characteristics of the Hydrosilicates Produced
                                   by the Hydration of C S, Il Cemento, 67:17–26 (1970)
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