Page 204 - Handbook of Gold Exploration and Evaluation
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Gold deposition in the weathering environment  179

            nature of the movement and susceptibility of slope materials to the action of
            freeze-thaw processes appears to depend upon the soil grain size distribution,
            permeability of the soil, rate of freezing and depth of frost penetration and
            availability of water. With increasing levels of saturation the development of
            positive pore pressure decreases cohesive resistance, which ultimately becomes
            negligible when the soil approaches complete saturation.
              Movement by solifluction is usually restricted to a few metres each year
            when seasonal thawing of the mantle in periglacial areas causes masses of
            material to break away, typically forming an eroded rock basin surrounding an
            armchair-like depression (cirque). Provided that movement first takes place on
            steeper slopes solifluction may occur on slopes as flat as two degrees or even
            less. The process is typical of periglacial weathering in arctic and alpine regions
            but may also occur in humid mountainous areas of the tropics. Andersson (1982)
            coined the term solifluction in his studies of the `mud glaciers' of Bear Island in
            the North Atlantic and `stone rivers' in the Falkland Islands. He described
            solifluction as slow flowing from higher to lower ground of soil or earth
            saturated with water, thereby distinguishing the process from the surface creep
            of unsaturated soils.


            Mud/debris flow
            Rapid mass-movement by mud/debris flow may occur on almost any slopes
            wherever the rainfall is seasonal or heavy. Periods of torrential rain cause
            weathered slope material to become saturated and behave more as a fluid than as
            a solid. This may take place in:
            · humid tropic areas where slope materials typically comprise unconsolidated
              debris of glacial or volcanic origin
            · frigid areas where the wedging action of freezing water disintegrates the
              near-surface rocks
            · humid temperate to tropic regions where source rocks, prior to uplift, are
              subjected to long periods of deep chemical weathering.


            3.6    Low-temperature aqueous geochemistry

            In order to understand the various chemical transformations involved in low-
            temperature aqueous solutions, the particular properties of the matrix and of the
            chemical composition of the gold must be known. Two important solution
            properties are acidity (pH) and the oxidation potential Eh. Acidity is usually
            measured as pH (the negative logarithm of the H +  concentration) and is
            controlled by the nature of the underlying geology, acidic or basic (see Section
                                            +
                                                                 ÿ
                               2ÿ
            1.1.2). Carbonates (CO 3 ), protons (H ) and bicarbonate (HCO 3 ) all exist in
            solution in controlled proportions. This control is defined in terms of equili-
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