Page 219 - Handbook of Gold Exploration and Evaluation
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190    Handbook of gold exploration and evaluation

              and high sulphide contents. Gold associated with tellurides or held in the lattice
              of the sulphides and other minerals may be released, but free gold remains
              immobile due to the absence of complexing ligands.
                 Saprolite is an upward extension of saprock, but one in which more than 20%
              of the weathered materials have been altered. Fine fabrics of weathered bedrock
              are retained but saprolitic materials tend to become more massive upwards as
              the proportion of clay increases. Cementation by secondary silica, carbonates,
              aluminosilicates and especially iron oxides is not uncommon. Gold deposits,
              formed either within the weathered ore zone or laterally dispersed into the wall
              rock consist primarily of secondary gold with residual primary gold confined to
              the lode system. Upgrading of a saprolite is similar to upgrading in an eluvial
              gold deposit in that original fabrics of the source rock are retained while mobile
              constituents of the rock are lost.


              Pedolith
              The four principal zones of the pedolith are the arenose zone, mottled zone,
              ferruginous zone (laterite) and soil. Although intensely weathered major struc-
              tural features such as quartz veins may be preserved, usually with some change
              in orientation (dip). In the arenose or plasmic zone, massive clays or sandy clays
              are developed. The mottled zone is characterised by blotches of Fe oxides,
              which may develop with further mobilisation into nodules and other secondary
              structures containing tubular voids. These nodules increase in number upward
              and in the ferruginous zone may be cemented together to form a duricrust.


              Post-lateritic modification
              Modifications of the pre-existing lateritic regoliths may occur by partial truncation
              or by cementation as they adjust to complex sequences of environmental change
              (Butt and Anand, 1997). Gold grains are gradually liberated and/or modified until
              ultimately, two different styles of gold may be present in the weathering profile,
              primary and supergene. If gold-silver alloys are more soluble than gold, primary
              gold enrichment will be preserved unless extreme conditions prevail. A marked
              depletion of gold at depths of about 5 m to 15 m over most mineralised units and
              lodes follows the repeated strong leaching of the upper saprolite. This has
              occurred even when the profile has been truncated (Butt, 1988).


              Partial truncation
              Erosion typically follows episodes of climatic change or drainage rejuvenation
              following uplift. It results in removal of part or all of the upper layers of the
              profile and may expose the lower horizons and unweathered rock to surface
              weathering. These fresh surfaces may themselves become the parent material of
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