Page 191 - Handbook of Hazardous Chemical Properties
P. 191

FERROUS OXALATE      181

              if large amounts are swallowed, promptly induce vomiting and get medical help. EYES: flush with
              plenty of water for at least 15 min.;  get medical help promptly if ill effect develop. SKIN: wash with
              soap and water;  Toxicity by Inhalation  (Threshold Limit  Value): 1 mg/m3 (as  iron);  Short-Tern
              Inhalation Limits: Data not available; Toxicity by Ingestion: Data not available; Late Toxicity: Grade
              2, LD,,  0.5 - 5 g/kg (rat); Vapor (Gas) Irritant Characteristics: Data not available; Liquid or Solid
              Im’tant Characteristics: Data not available; Odor I;hreshold Data not available.
              Fire Hazards - Flash Point  : Not  flammable; Flammable Limits in Air  (36):  Not flammable; Fire
              Extinguishing Agents:  Not pertinent; Fire Extinguishing Agents Not To Be Used: Not pertinent; Special
              Hazards of  Combustion Products: Irritating hydrogen chloride fumes may form in fire; Behavior in
              Fire: Not pertinent; Ignition Temperature : Not pertinent; Electrical Hazard: Not pertinent; Burning
              Rate: Not pertinent.
              Chemical Reactivity - Reactivity with Water: No reaction; Reactivity with Common Materials: Solution
              may corrode metals; Stability During Transport: Stable; Neutralizing Agents for Acicis and Caustics:
              Flush with water, rinse with dilute solution of sodium bicarbonate or soda ash; Polymerization: Not
              pertinent; Inhibitor of Polymerization: Not pertinent.

              FERROUS F’LUOROBORATE
              Chemical Designations - Synonyms: Ferrous borofluoride; Chemical Fonnula: Fe@F&-&O.
              Observable Characteristics - Physical State (as shipped): Liquid; Color: Yellow-green; Odor: Data
              not available.
              Physical and Chemical Properties - Physical State at I5 “c and I arm. : Liquid; Molecular Weight:
             229.5 (solute only); Boiling Point at I atm. : Not pertinent (decomposes); Freezing Point: Not pertinent;
              Critical Temperature: Not pertinent; Critical Pressure: Not pertinent; Specific Gravity: (est.) > 1.1 at
             20 “C, (liquid); Vapor (Gar) SpeciJic Gravity: Not pertinent; Ratio ofSpeciJc Heats of Vapor (Gas):
              Not pertinent; Latent Heat of Vaporization: Not pertinent; Heat of Combustion: Not pertinent; Heat of
             Decomposition: Not pertinent.
             HeaIth Hazards Information - Recommended Personal Protective Equipment: Goggles or face shield,
             rubber  gloves;  Symptoms Following Exposure: Ingestion causes irritation of mouth  and  stomach.
             Contact with eyes or skin causes irritation; General Treatment for Exposure: INGESTION: give large
             amount of water; induce vomiting; get medical attention. EYES: flush with water for at least 15 min.
             SKIN: flush with water; Toxicity by Inhalation (Threshold Limit Value): 1 mg/m3 (as iron); Short-Tenn
             Inhalation Limits:  Data not available; Toxicity by Ingestion: Data not available; Late Toxicity: Data not
             available;  Vapor  (Gas) Irritant  Characteristics:  Data  not  available;  Liquid  or  Solid  Irritant
              Characteristics: Data not available; Odor i%reshold: Data not available.
             Fire Hazards - Flash Point  : Not  flammable; Flammable Limits in Air (W):  Not flammable; Fire
             Extinguishing Agents: Not pertinent; Fire Extinguishing Agents Not To Be Used: Not pertinent; Special
             Hazarcis of Combustion Products: Not pertinent; Behavior in Fire: Not pertinent; Ignition Temperature
              : Not pertinent; Electrical Hazard: Not pertinent; Burning Rate: Not pertinent.
             Chemical Reactivity - Reactivity with Water: No reaction; Reactivity with Common Materials: No
             reaction; Stability During Transport: Stable; Neutralizing Agents for Acik and Caustics: Not pertinent;
             Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

             FERROUS OXALATE
             Chemical Designations - Synonyms: Ferrous oxalate dihydrate, Ferrox, Iron protoxalate, Oxalic acid
             (ferrous salt); Chemical Formula: FeC,0,.2Hz0.
             Observable Characteristics - Physical State (as shipped): Solid; Color: Pate yellow; Odor: None.
             Physical and Chemical Properties - Physical State at I5 “c and  I  atm. : Solid; Molecular Weight:
             179.9; Boiling Point at I  atm.: Not pertinent (decomposes); Freezing Point: Not pertinent; Critical
             Temperature: Not pertinent; Critical Pressure: Not pertinent; SpeciJic Gravity: 2.3 at 20 “C, (solid);
             Vapor (Gas) Specijic Gravity: Not pertinent; Ratio of Specijic Heats of Vapor (Gas): Not pertinent;
             Latent Heat of Vaporization: Not pertinent; Heat of Combustion: Not pertinent; Heat ofDecomposition:
             Not pertinent.
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