Page 205 - Handbook of Hazardous Chemical Properties

1-HEPTENE 195

reactions; Stability During Trmport: Stable; Neutralizing Agents forAcids and Caustics: Not pertinent;
Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

HEPTANOL
Chemical Designations - Synonyms: Enanthic alcohol; 1-Heptanol; Heptyl alcohol; 1-Hydroxyheptane;
Chemical Formula: CH,(CH&H,OH.
Observable Characteristics - Physical State (as shipped): Liquid; Color: Colorless; Odor: Weak
alcoholic.
Physical and Chemical Properties - Physical State at 15 "c and I am. : Liquid; Molecular Weight:
116.20; Boiling Point at I abn.: 349, 176, 449; Freezing Point: -29, -34, 239; Critical Temperature:
680, 360, 633; Critical Pressure: 440,30, 3.0; Specific Gravity: 0.822 at 20°C, (liquid); Vapor (Gas)
Specific Gravity: Data not available; Ratio of Specific Heats of Vapor (Gas): 1.049; Latent Heat of
Vaporization: 189, 105,4.40; Heat of Combustion: -18,810, -8784, -367.8; Heat of Decomposition:
Not pertinent.
Health Hazards Information - Recommended Personal Protective Equipment: Chemical goggles or
face shield; Symptoms Following Exposure: Low toxicity; liquid may irritate eyes; General Treatment
for Exposure: Flush all affected parts with plenty of water; Toxicity by Inhalation (Threshold Limit
Value): Data not available; Short-Tern Inhalation Limits: Data not available; Toxicity by Ingestion:
Grade 2; oral rat LD,, = 1.87 glkg; Late Toxicity: Data not available; Vapor (Gas) Irritant
Characteristics: Nonirritating; Liquid or Solid Im'tant Characteristics: Liquid may irritate eyes; it is
not irritating to skin; Odor Threshold: 0.49 ppm.
Fire Hazards - Flash Point (deg. F): 170 OC; Flammable Limits in Air (W): No data; Fire
Extinguishing Agents: Foam, carbon dioxide, or dry chemical; Fire Extinguishing Agents Not To Be
Used: Not pertinent; Special Hazards of Combustion Products: Not pertinent; Behavior in Fire: Not
pertinent; Ignition Temperature : No data; Electrical Hazard: Not pertinent; Burning Rate: 3.2
mm/min.
Chemical Reactivity - Reactivity with Water: No reaction; Reactivity with Common Materials: No
reactions; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent;
Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

1-HEFTFdNE
Chemical Designations - Synonyms: Heptylene; Chemical Formula: CH,(CH,),CH= CH,,
Observable Characteristics - Physical State (as shipped): Liquid; Color: Colorless; Odor: Like
gasoline.
Physical and Chemical Properties - Physical State at 15 "C and I atm. : Liquid; Molecular Weight:
98.18; Boiling Point at I am.: 200.5, 93.6, 366.8; Freezing Point: -182, -119, 154; Critical
Temperature: 507.4, 264.1, 537.3; Critical Pressure: 420, 28.57, 2.89; Specific Gravity: 0.697 at
20°C (liquid); Vapor (Gas) Qecijic Gravity: 3.4; Ratio of Specijic Heats of Vapor (Gas): 1.057;
Latent Heat of Vaporization: 137, 76.3, 3.20; Heat of Combustion: -19,377, -10,765, -450.71; Heat
of Decomposition: Not pertinent.
Health Hazards Information - Recommended Personal Protective Equipment: Safety goggles or face
shield; similar to gasoline; Symptoms Following Qvosure: High concentrations may produce slight
irritation of eyes and respiratory tract; may also act as simple asphyxiate and slight anesthetic; General
Treatment for Exposure: Remove from exposure. Administer artificial respirator if needed; Taicity
by Inhalation (Threshold Limit Value): Data not available; Short-Term Inhalation Limits: Data not
available; Toxicity by Ingestion: Data not available; Late Toxicity: Data not available; Vapor (Gas)
Irritant Characteristics: Vapors cause a slight smarting of the eyes or respiratory system if present in
high concentrations. The effect is temporary; Liquid or Solid Im'fant Characteristics: Minimum hazard.
If spilled on clothing and allowed to remain, may cause smarting and reddening of the skin; Odor
Threshold Data not available.
Fire Hazards - Flash Point (deg. F): 25 CC; Flammable Limits in Air (%): 1.0 (LEL); Fire