Page 254 - Handbook of Hazardous Chemical Properties
P. 254
244 MERCURIC AMMONIUM CHLORIDE
causes irritation and ulceration. Skin contact may cause dermatitis. Ingestion causes pain, vomiting,
ulceration of mouth and stomach, kidney failure, metallic taste, pallor, and rapid, weak pulse; General
TreatmentforExposure: Have physician treat for mercury poisoning. EYES or SKIN: flush with water.
INGESTION: call physician; poison should be removed from stomach as soon as possible; give milk
or white of eggs beaten with water, than tablespoon of salt in a glass of warm water and repeat until
vomit fluid is clear; repeat milk or white of eggs beaten with water; Toxicity by Inhalation (ThreshoM
Limit Value): 0.05 mg/m3 (as mercury); Short-Tern Inhalation Limits: No data; Toxicity by Ingestion:
Grade 3; oral LD,, = 76 mg/kg (rat); Late Toxicity: Intestinal bleeding and kidney damage may
develop; Vapor (Gas) Irritant Characteristics: Not pertinent; Liquid or Solid Irritant Characteristics:
No data; Odor i%reshold Not pertinent.
Fire Hazards - Flash Point : Not flammable; Flammable Limits in Air (%): Not flammable; Fire
Extinguishing Agents: Not pertinent; Fire Extinguishing Agents Not To Be Used: Not pertinent; Special
Hazards of Combustion Products: Smoke may contain toxic mercury or mercury oxide fumes; Behavior
in Fire: Not pertinent; Ignition Temperature : Not pertinent; Electrical Hazard: Not pertinent; Burning
Rate: Not pertinent.
Chemical Reactivity - Reactivity with Water: No reaction; Reactivity with Comn Materials: No
reaction; Stability During Tmport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent;
Polymrization: Not pertinent; Inhibitor of Polymerization: Not pertinent.
MERCURIC AMMOMUM CHLORIDE
Chemical Designations - Synonyms: Albus; Aminomercuric chloride; Ammoniated mercury; Mercuric
chloride, ammoniated; Mercury ammonium chloride; Mercury (Il) chloride ammonobasic; Chemical
Formula: HgNHJl.
Observable Characteristirs - Physical State (as shipped): Solid; Color: White; Odor: None.
Physical and Chemical Properties - Physical State at 15 "c and I atm. : Solid; Molecular Weight:
252.1; Boiling Point at 1 atm.: Not pertinent (sublimes at red heat); Freezing Point: Not pertinent
(infusible); Critical Temperature: Not pertinent; Critical Pressure: Not pertinent; Specijic Gravity: 5.7
at 20 "C (solid); Vapor (Gas) SpecGc Gravity: Not pertinent; Ratio ofSpecipc Heats of Vapor (Gas):
Not pertinent; Latent Heat of Vaporization: Not pertinent; Heat of Combustion: Not pertinent; Heat of
Decomposition: Not pertinent.
Health Hazards Information - Recommended Personal Protective Equipment: Gloves, goggles,
respirator; Symptoms Following Exposure: The general symptoms are those of mercury poisoning,
developing rapidly after ingestion but more slowly after low repeated exposures. Contact with eyes
causes irritation and ulceration. Skin contact may cause dermatitis. Ingestion causes pain, vomiting,
ulceration of mouth and stomach, kidney failure, metallic taste, pallor, and rapid, weak pulse; General
Treatment forfiposure: Have physician treat for mercury poisoning. EYES or SKIN: flush with water.
INGESTION: call physician; poison should be removed from stomach as soon as possible; give milk
or white of eggs beaten with water, than tablespoon of salt in a glass of warm water and repeat until
vomit fluid is clear; repeat milk or white of eggs; Toxicity by Inhalation (ThresholdLimit Value): 0.05
mg/m3 (as mercury); Short-Term Inhalationlimits: No data; Toxicity by Ingestion: Grade 3; oral LD,
= 76 mg/kg (rat); Late Toxicity: Intestinal bleeding and kidney damage may develop; Vapor (Gas)
Irritant Characteristics: Data not available; Liquid or Solid Irritant Characteristics: No data; Odor
i7ireshold Not pertinent.
Fire Hazards - Flash Point : Not flammable; Flammable Limits in Air (%): Not flammable; Fire
Extinguishing Agents: Not pertinent; Fire Extinguishing Agents Not To Be Used: Not pertinent; Special
Hazards of Combustion Products: Smoke may contain toxic mercury compounds; Behavior in Fire: Not
pertinent; Ignition Temperature : Not pertinent; Electrical Hazard: Not pertinent; Burning Rate: Not
pertinent.
Chemical Reactivity - Reactivity with Water: No reaction; Reactivity with Comn Materials: No
reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent;
Polymerization: Not pertinent; Inhibitor of Polymerim*on: Not pertinent.