Page 33 - Handbook of Hazardous Chemical Properties

ANISOYL CHLORIDE 23

allowed to remain, may cause smarting and reddening of the skin; Odor Threshold 0.067 ppm.
Fire Hazards - Flash Point (deg. F): (iso-): 69 CC (n-); 91 CC; Flammable Limits in Air (%): 1.1 -
7.5; Fire Extinguishing Agents: alcohol foam, dry chemical, carbon dioxide; Fire Extinguishing Agents
Not To Be Used Water in straight hose stream will scatter and spread fire and should not be used;
Special Hazards of Combun'on Products: Not pertinent; Behavior in Fire: Not pertinent; Ignition
Temperature (deg. F): 572 (n); Electrical Hazard Not pertinent; Burning Rate: 4.1 dmin.
Chemical Reactivity - Reactivity with Water: No reaction; Reactivity with Common Materials: No
reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent;
Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

ANILINE
Chemical Designations - Synonyms: Aminobenzene; Aniline Oil; Blue Oil; Phenylamine; Chemical
Formula: C,H,NH2.
Observable Characteristics - Physical State (as normally shipped): Liquid; Color: Colorless to pale
brown; Odor: Aromatic amine like; characteristic, peculiar; strongly amine-like.
Physical and Chemical Properties - Physical State at 15 'C and I atm. : Liquid; Molecular Weight
93.13; Boiling Point at I atm.: 363.6, 184.2, 457.4; Freezing Point: 21, -6.1, 267.1; Critical
Temperature: 798.1,425.6,698.8; Critical Pressure: 770,52.4,5.31; Specific Gravity: 1.022 at2O"C
(liquid); Vapor (Gas) Density: Not pertinent; Ratio of Specific Heats of Vapor (Gas): 1.1; Latent Heat
of Vaporizm'on: 198, 110,4.61; Heat of Combustion: -14,980, -8320, -348,3; Heat ofDecomposition:
Not pertinent.
Health Hazards Information - Recommended Personal Protective Equipment: Respirator for organic
vapors, splashproof goggles, rubber gloves, boots; Symptoms Following Exposure: ACUTE
EXPOSURE: blue discoloration of fmger-tips, cheeks, lips and nose; nausea, vomiting, headache and
drowsiness followed by delirium, coma and shock. CHRONIC EXPOSURE: loss of appetite, loss of
weight, headaches,, visual disturbances; skin lesions; Geneml Treatment for Exposure: Remove victim
to fresh air and call a physician at once. SKIN OR EYES: immediately flush skin or eyes with plenty
of water for at least 15 min. If cyanosis is present, shower with soap and warm water, with special
attention to scalp and fingernails; Toxicity by Inhalation (Threshold Limit Value): 5 ppm; Short-Tern
Exposure Limits: 50 ppm for 30 min.; 5 ppm for 8 hr.; Toxicity by Ingestion: Grade 3; LD,, 5 to 500
mg/kg; Lute Toxicity: None recognized; Vapor (Gas) Irritant Characteristics: Vapors cause a slight
smarting of the eyes or respiratory system if present in high concentrations. The effect is temporary;
Liquid or Solid Irritant Characteristics: If spilled on clothing and allowed to remain, may cause
smarting and reddening of the skin.; Odor Threshold: 0.5 ppm.
Fire Hazards - Flash Point (deg. F): 168 OC; 158 CC; Flammable Limits in Air (%): 1.3 (LEL); Fire
Extinguishing Agents: Water, foam, dry chemical or carbon dioxide; Fire EKtinguishing Agents Not To
Be Used Not pertinent; Special Hazards of Combustion Products: Toxic vapors are generated when
heated; Behavior in Fire: Not pertinent; Ignition Temperature (deg. F): 1418; Electrical Hazard Not
pertinent; Burning Rate: 3.0 dmin.
Chemical Reactivity - Reactivity with Water: No reaction; Reactivity with Common Materials: No
reaction; stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Flush with
water and rinse with dilute acetic acid; Polymeriz&'on: Not pertinent; Inhibitor of Polymeriultion: Not
pertinent.

ANISOYL CHLORIDE
Chemical Designations - Synonyms: p-Anisoyl Chloride; Chemical Formula: p-CH,OC,H,COCl.
Observable Characteristics - Physical State (as normally shipped): Liquid; Color: Yellow; brown;
Odor: Sharp, penetrating.
Physical and Chemical Properties - Physical State at 15 'C and I atm. : Liquid; Molecular Weight:
171.6; Boiling Point at I atm.: 504,262,535; Freezing Point: 72,22,295; Critical Temperature: Not
pertinent; Critical Pressure: Not pertinent; Speci@c Gravity: 1.26 at 20°C (liquid); Vapor (Gas)
Density: Not pertinent; Ratio of @ecific Heats of Vapor (Gas): Not pertinent; Latent Heat of