Page 360 - Handbook of Hazardous Chemical Properties
P. 360
350 SODIUM CACODYLATE
Characteristics: Non-volatile; Liquid or Solid Irritant Characteristics: Irritates skin; Odor Z?ireshoM:
Not pertinent.
Fire Hazards - Flash Point : Not flammable; Flammble Limits in Air (96): Not pertinent; Fire
Extinguishing Agents: Graphite, limestone, soda ash, sodium chloride powders; Fire Extinguishing
Agents Not To Be Used: Water, carbon dioxide, or halogenated extinguishing agents; Special Hazards
of Combustion Products: Not pertinent; Behavior in Fire: Decomposes and produces highly flammable
hydrogen gas; Ignition Temperature : Not pertinent; Electrical Hazard: Not pertinent; Burning Rate:
Not pertinent.
Chemical Reactivity - Reactivity with Water: Ream to form flammable hydrogen gas; Reactivity with
Common Materials: Reacts with acids to form toxic, flammable diborane gas. Slowly attacks and
destroys glass; Stability During Transport: Stable unless contaminated with acids or is overheated,
thereby forming flammable hydrogen gas; Neutralizing Agents forAcids and caustics: Caustic formed
by the reaction with water can be diluted with water and then neutralized with acetic acid;
Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.
SODIUM CACODnATE
Chemical Designations - Synonym: Arsecodile; Arsicodile; Arsycodile; Phytar 160; Phytar 560;
Sodium dimethylarsonate; Chemical Formula: (CH,),AsOONa.
Observable Characteristics - Physical State (as normally shipped): Solid or water solution; Color:
Colorless to light yellow; Odor: None.
Physical and Chemical Properties - Physical State at 15 “c and I atm. : Solid; Molecular Weight:
160.0; Boiling Point at I atm.: Not pertinent (decomposes); Freezing Point: Not pertinent; Critical
Temperature: Not pertinent; Critical Pressure: Not pertinent; Specijic Gravity: (est.) > 1 at 20 “C
(solid); Vapor (Gas) Density: Not pertinent; Ratio of Speczjic Heats of Vapor (Gus): Not pertinent;
Lutent Heat of Vaporization: Not pertinent; Heat of Combustion: Not pertinent; Heat of Decomposition:
Not pertinent.
Health Hazards Information -Recommended Personal Protective Equipment: Goggles or face shield:
dust mask: rubber gloves; Symptom FollowingExposure: Dust may irritate eyes. Ingestion or excessive
inhalation causes irritation of stomach and intestines with nausea, vomiting, diarrhea, shock, rapid
pulse, coma; General Treatment for Exposure: INHALATION: remove victim from exposure: call
physician. EYES: flush with water. SKIN: flush with water and wash well with soap and water.
INGESTION: call physician: induce evacuation of intestinal tract by inducing vomiting, giving gastric
lavage and a saline cathartic. Do NOT use BAL as an antidote; Toxicity by Inhalation: No data; Short-
Tern Exposure Limits: Data not available; Toxicity by Ingestion: Grade 2, oral LD,, = 2,600 mg/kg
(rat); Lute Toxicity: Data not available; Vapor (Gas) Zm’tant Characteristics: Data not available; Liquid
or Solid Im*tanf Characteristics: Data not available; Odor i%reshold Not pertinent.
Fire Hazards - Flash Point : Not flammable; Flammable Limits in Air (96): Not flammable; Fire
Extinguishing Agents: Not pertinent; Fire Extinguishing Agents Not To Be Used: Not pertinent; Special
Hazards of Combustion Products: Arsenic containing fumes are formed in fires; Behavior in Fire: Not
pertinent; Ignition Temperature : Not pertinent; Electrical Hazard: Not pertinent; Burning Rate: Not
pertinent.
Chemical Reactivity - Reactivity with Water: No reaction; Reactivity with Comn Materials:
Corrodes many common metals but the reaction is non-hazardous; Stability During Transport: Stable;
Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of
Polymerization: Not pertinent.
SODIICIM CHLORATE
Chemical Designations - Synonym: Chlorate of soda; Chemical Foda: NaC103.
Observable Characteristics -Physical State (as normally shipped): Solid; Color: Pale yellow to white;
Odor: Odorless.
Physical and Chemical Properties - Physical State at 15 “c and I a&z. : Solid; Molecular Weight:
106.45; Boiling Point at I am.: Decomposes; Freezing Point: 478, 248, 521; Critical Temperature: