Page 393 - Handbook of Hazardous Chemical Properties

TURPENTINE 383

Hazard: No data; Burning Rate: No data.
Chemical Reactivity -Reactivity with Water: No reaction; Reactivity with Comn Materials: May
attack some forms of plastics and elastomers; Stability During Transport: Stable; Neutralizing Agents
for Acids and Caustics: Not pertinent; Polymrizm'on: Not pertinent; Inhibitor of Polymrim'on: Not
pertinent.
TRIS(AZIRIDINYL)PHOSPHINF, OXIDE
Chemical Designations - Synonyms: APO; Phosphoric acid triethileneimide; Triethylenephosphor-
amide; Tris (1-aziridinyl) phosphin oxide; Chemical Formula: (CH,CH$I),PO or C,H,,N,PO.
Observable Characteristics - Physical State (as nomlly shipped): Solid; Color: White; Odor: Data
not available.
Physical and Chemical Properties - Physical State at I5 "c and I am. : Solid; Molecular Weight:
173.16; Boiling Point at I atm.: Not pertinent (decomposes); Freezing Point: 106, 41, 314; Critical
Temperamre: Not pertinent; Critical Pressure: Not pertinent; specific Gravity: (est.) > 1 at 20 "C
(solid); Vapor (Gas) Density: Not pertinent; Ratio of Specijic Heats of Vapor (Gas): Not pertinent;
Latent Heat of Vaporization: Not pertinent; Heat of Combustion: Not pertinent; Heat ofDecomposition:
Not pertinent.
Health Hazards Information - Recommended Personal Protective Equipment: Protective clothing and
gloves to prevent contact with skin; goggles; Symptoms Following Exposure: Inhalation (unlikely unless
a heave mist is formed ) causes symptoms similar to the those observed after ingestion. Contact with
liquid or powder causes irritation of eyes and (on prolonged contact) irritation and burns of skin. Burns
are slow to develop and slow to heal. May sensitize on repeated contact. Ingestion causes depression,
anorexia and diarrhea, appearing 2-3 days before death, followed by terminal dyspnea, incoordination,
epistaxis, salivation and cyanosis; General Treatment for Exposure: INHALATION: remove victim to
fresh air. EYES: flush with water at once for at least 15 min.; get medical attention. SKIN: flush with
water at once, followed by vinegar and dilute hydrogen peroxide. INGESTION: only symptomatic and
supportive measured are available; Toxicity by Inhalation (Threshold Limit Value): Data not available;
Short-Tern Exposure Limits: Data not available; Toxicity by Ingestion: Grade 4, oral rat LD,=37
mglkg; Late Toxicity: None observed; Vapor (Gas). Irritant Characteristics: Data not available; Liquid
or Solid Irritant Characteristics: Data not available; Odor l7zreshold Data not available.
Fire Hazards - Fi'ash Point : Not flammable; Flammable Limits in Air (56): Not flammable; Fire
Extinguishing Agents: Not pertinent; Fire Extinguishing Agents Not To Be Used: Not pertinent; Special
Hazardr of combustion Products: Phosphoric acid mist may form in fires. Toxic oxide of nitrogen may
form; Behavior in Fire: No data; Ignition Temperature : Not pertinent; Electrical Hazard: Not
pertinent; Burning Rate: Not pertinent.
Chemical Reactivity - Reactivity with Water: No reaction unless in the presence of acids and caustics;
Reactivity with Common Materials: Slow decomposition occurs, but generally the reactions are not
hazardous; Stability During Transport: Stable if cool; Neutralizing Agents for Acib and Caustics: Not
pertinent; Polymerization: Violent, exothermic polymerization occurs at about 225 of. Acid fumes will
also cause polymerization at ordinary temperatures; Inhibitor of Polymerization: None reported.

TURPENTINE
Chemical Designations - Synonyms: D.D. turpentine, Gum turpentine, Spirits of turpentine, Sulfate
turpentine, Turps, Wood turpentine; Chemical Formula: C,,,HH,,.
Observable Characteristics - Physical State (as nomlly shipped): Liquid; Color: Colorless; Odor:
Aromatic, rather unpleasant, penetrating.
Physical and Chemical Properties - Physical State at I5 "c and I atm. : Liquid; Molecular Weight:
Not pertinent; Boiling Point at I atm.: 302-320, 150-160, 423-433; Freezing Point: Not pertinent;
Critical Temperature: Not pertinent; Critical Pressure: Not pertinent; Specific Gravity: 0.86 at 15 "C;
Vizpor (Gus) Density: Not pertinent; Ratio of Specijic Heas of Vapor (Gas): Not pertinent; Latent Heat
of Vaporizm'on: Not pertinent; Heat of Combustion: Data not available; Heat of Decomposition: Data
not available.