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Section 1.2
                                                     GLASS LASERS



                         1.2.1  Introduction


                            The past two decades have witnessed increased activity in glass lasers, in the form of both
                         bulk materials and fiber and planar waveguides. Fibers, with their long interaction region,
                         and heavy metal fluoride glasses, with their low vibrational frequencies and hence reduced
                         probabilities for decay by nonradiative processes, have  made  possible  many  new  lasing
                         transitions and operation at longer wavelengths. Upconversion pumping schemes, laser diode
                         pumping, and double-clad fibers have further extended the ulitization of glass lasers.
                            Glass lasers and amplifiers have been based almost exclusively on the trivalent lanthanide
                         ions. Ions and host glasses that have been used for lasers are summarized in Table 1.2.1.
                         The energy levels, lasing transitions, and approximate wavelengths of lanthanide-ion glass
                         lasers are shown in Figures 1.2.1(a) and 1.2.1(b).


                                                        Table 1.2.1
                                           Host Glass Types and Laser Ions
                                               3+    3+     3+    3+    3+    3+    3+     3+    3+
                             Glass Type      Pr    Nd    Pm    Sm     Tb    Ho    Er    Tm     Yb

                         Oxide Glasses
                            borate                   •                 •                        •
                            germanate                •                       •            •
                            phosphate                •     •                       •
                            silica             •     •           •           •     •     •      •
                            silicate                 •                       •     •     •      •
                            aluminosilicate                                        •
                            borosilicate             •                             •
                            germanosilicate                                                     •
                            tellurite                •

                         Halide Glasses
                            fluoroberyllate          •
                            fluorozirconate    •     •                       •     •      •     •


                         Oxyhalide Glasses
                            fluoroaluminate          •                             •
                            fluorophosphate          •                             •

                               Chalcogenide Glasses
                            sulfide                  •










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