Page 383 - Instant notes

Index 369

Force constant, 251, 255
Formal cell reaction, 106–108, 111
Formal charge, 100, 118
Franck-Condon principle, 260
Free electron model, 227
Free energy, 48–49, 52, 74, 77, 83, 97, 108
definition, 48
general properties of, 48–49
liquid surface, 15
molar, see Chemical potential
of activation, 140
relation to available work, 48–49
relation to entropy change, 49
spontaneity, 49
temperature dependence, 49, 50
Free radical, 153
Freezing point, 82–83
curve, 89
depression, 79–80
Freezing temperature, 82
Frictional coefficient, 14
Fugacity, 54, 104
Fusion, 161
standard enthalpy of, 79

γ-ray, 164
Galvanic cell, 103
Gas, 1–11
gas constant, 2
relation to Boltzmann constant, 7
laws, 1–2
non ideal, 8–11
perfect, 1–2
vapor pressure, 56
Gas cavity, 15
internal pressure, 15
Gas electrode, 104
Gerade, 222
Gibbs free energy, see Free energy
Gibbs function, see Free energy
Gibbs-Helmholtz equation, 49, 50
Glass electrode, 112
Glass frit, 103, 106, 112
Graham’s law of effusion, 6
Gray, 163
Grotthus mechanism, 119
Ground state, 191

Half-cell, 102
ferric-ferrous, 104
fluorine-fluoride, 104