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96    4  ·  Foliations, Lineations and Lattice Preferred Orientation

                    Box 4.8  Area and volume change             leading to spaced foliation (e.g. Fig. 4.14). In most cases,
                                                                microfolds (mechanical rotation) develop in the dia-
                    In geological practice, it is easy to confuse area change and vol-  genetic foliation and this initial stage is followed by solu-
                    ume change. Area change is a component of two-dimensional
                    strain and is measured in a plane, e.g. from stretch values; it  tion transfer of material between hinges and limbs, usu-
                    causes a change in the cross-sectional area of a structure (e.g. a  ally quartz from limbs to hinges (Williams 1972a; Cos-
                    fossil). Volume change is a component of three-dimensional  grove 1976; Gray 1979; Waldron and Sandiford 1988), and/
                    strain. Area change is not a direct measure for volume change.  or syntectonic crystallisation or recrystallisation of mi-
                    For example, even if a thin section shows evidence for area in-  cas in cleavage domains (Tullis 1976; White and Knipe
                    crease, bulk volume loss may occur if shortening is significant
                    in the direction normal to the thin section. Only if strain is  1978; Knipe 1981; White and Johnston 1981; Lee et al. 1986;
                    two-dimensional, i.e. if stretch normal to the plane of observa-  Kisch 1991). These effects are thought to be mainly tem-
                    tion equals 1 (plane strain), can area change be used as a meas-  perature-dependent, solution transfer occurring at lower
                    ure of volume change (Fig. 4.32).           grade than syntectonic crystallisation and recrystallisa-
                                                                tion (Kanagawa 1991; Kisch 1991). Consequently, solution
                                                                transfer may be followed by syntectonic crystallisation
                   served graptolites that permit the measurement of abso-  (Weber 1981). With increasing temperature in the absence
                   lute finite strains (Goldstein et al. 1998) constitute an ex-  of deformation, a preferred orientation may even be
                   ception. The significance of volume change may in some  strengthened further by mimetic mica growth (Siddans
                   cases be overestimated since evidence of shortening nor-  1977; Weber 1981; Ishii 1988). In some slates, the stage of
                   mal to a foliation (partly dissolved structures and fossils;  folding and rotation may be absent and the foliation de-
                   Fig. 4.21) is usually clear, while evidence of extension par-  velops by syntectonic crystal growth without mechanical
                   allel to the foliation (e.g. fibres around pyrite, boudinaged  rotation (Woodland 1982; Gregg 1985; Ishii 1988).
                   micas) is easily overlooked (Fig. 4.32).        After a first foliation is developed, renewed shorten-
                     Crenulation cleavage development is probably associ-  ing at a low angle to the existing foliation may cause de-
                   ated with volume increase of microlithons and volume  velopment of a second foliation; again, the early foliation
                   decrease of cleavage domains while bulk deformation may  may be folded or truncated by developing new cleavage
                   be approximately volume-constant (Fig. 4.32; Erslev and  domains, and either solution transfer or new growth of
                   Mann 1984; Lee et al. 1986; Waldron and Sandiford 1988;  mica and possibly other minerals such as plagioclase
                   Bhagat and Marshak 1990; Wintsch et al. 1991; Manckte-  (Williams et al. 2001) may dominate. This leads to dis-
                   low 1994; Stewart 1997; Saha 1998). Quartz, albite and, to  junctive or crenulation cleavage. If differentiation is strong
                   a lesser extent, micas are exchanged in pelites while zir-  and accompanied by recrystallisation, evidence of early
                   con, apatite and rutile are largely inert (Southwick 1987;  foliations may be obscured and a compositional layering
                   Waldron and Sandiford 1988; Williams et al. 2001). In  develops. The term differentiated layering is also com-
                   many rocks, solution transfer may therefore only occur  monly used for such structures, but since it can be diffi-
                   on a small scale and spacing of foliation may actually de-  cult to distinguish sedimentary layering from secondary
                   pend on the distance over which solution transfer is ca-  layering, the non-genetic term compositional layering is
                   pable of maintaining strain compatibility in a deforming  preferred.
                   rock (Waldron and Sandiford 1988).              In psammites, continuous foliation can form in fine-
                                                                grained rocks, or spaced foliations in coarse-grained
                   4.2.9.4                                      material (Gray 1978). In the second case, mica films
                   Foliations, Lithotype and Metamorphic Conditions  (Fig. 4.23b) may develop by solution transfer and mica
                                                                growth (Gregg 1985) and/or by the development of mi-
                   Secondary foliations develop by processes mentioned in  cro shear zones (Goodwin and Tikoff 2002).
                   Sect. 4.2.7, but in different lithotypes and under different  In limestones, foliation development is strongly de-
                   metamorphic conditions, these processes operate to differ-  pendent on temperature and mica-content. Solution
                   ent extents. A brief outline of present ideas is given below.  transfer and twinning are important at low temperature
                     In pelites, mechanical rotation, pressure solution trans-  (Sect. 3.12.3; Davidson et al. 1998) and can lead to a grain
                   fer, crystallisation, recrystallisation and oriented nucleation  shape preferred orientation defined by elongated carbon-
                   are all competing processes. In many cases, a diagenetic fo-  ate grains, or a coarse spaced foliation (stylolites). A pri-
                   liation may have been present before onset of foliation  mary high mica content of limestone may cause develop-
                   development. In some cases, at very low-grade or non-  ment of slaty cleavage and cleavage bundles. In one case
                   metamorphic conditions, cleavage domains develop ob-  the growth of illite + kaolinite + quartz + anatase in cleav-
                   lique to the diagenetic fabric by stress-induced solution  age domains was reported to accompany the removal of
                   transfer or development and rotation of micro shear zones  calcite by dissolution (Davidson et al. 1998). Passive rota-
                   (Goodwin and Tikoff 2002) with no- or minimal folding,  tion of micas is mainly responsible for mica-preferred
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