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3.14  ·  Flow Laws and Deformation Mechanism Maps  63
                 concentrated in the mantle, which grows in volume as the  2001; Mainprice et al. 2003). Some important and com-
                 core shrinks with progressive deformation (Dell’Angelo  monly quoted types of flow laws are given in Box 3.11. In
                 and Tullis 1989). Diffusion processes may also play a role  the equation for dislocation creep given here, strain rate
                 in the recrystallised mantles. In quartz, dislocation creep  is independent of grain size but has a strong non-linear
                 is accommodated by dislocation climb and SGR recrys-  (power law) dependence of strain rate on stress. In the
                 tallisation dominates. The new grains have the same dis-  equations for diffusion creep, strain rate has a linear de-
                 location density as old subgrains, and the new aggregate  pendence on stress but a non-linear dependence on grain
                 is equally strong as the old grains; consequently, no core  size. Flow laws have been proposed on the basis of ex-
                 and mantle structure develops and quartz deforms rela-  periments and theoretical considerations.
                 tively homogeneously.                           The parameters in the equations have been determined
                                                               experimentally for a range of conditions. In many cases,
                 3.13.3                                        these data are incomplete or difficult to compare because
                 Deformed Rhyolites – an Exception             of differences in confining pressure, sample preparation
                                                               etc. However, if a suitable set of data on rheology of a par-
                 Some deformed rhyolites and ignimbrites are an inter-  ticular mineral can be found, it is possible to integrate
                 esting exception to the rule that in quartz-feldspar ag-  the data to determine which mechanisms are expected to
                 gregates, deformed at low- to medium-grade conditions,  operate under particular conditions; in general, the
                 quartz is the weaker mineral. In these rocks, quartz  mechanism that operates at the lowest differential stress
                 phenocrysts may survive as porphyroclasts (Figs. 3.7, 3.9,  for a particular strain rate is thought to be dominant.
                 3.10; Williams and Burr 1994). Probably, the fine-grained  Conditions at which specific deformation mechanisms are
                 polymineralic matrix of a rhyolite can deform by grain  dominant can be shown in a deformation mechanism map.
                 boundary sliding, or pressure solution and precipitation  Such a map shows fields in which certain deformation
                 at such a low differential stress that limited intracrystal-  mechanisms are dominantly, although not exclusively, ac-
                 line deformation is induced in quartz. Deformed rhyolites  tive. Also shown are projected curves for several strain rates,
                 and ignimbrites can be recognised by the presence of  which give an indication of the relationship of stress and
                 euhedral to subhedral quartz phenocrysts with typical  strain rate for a specific temperature. Cataclasis occurs only
                 wriggly embayments (Figs. 3.9, 3.10). Obviously, the be-  above a certain differential stress level, which is dependent
                 haviour of quartz and feldspar in an aggregate is depend-  on fluid pressure (Sibson 1977a) and temperature (Griggs
                 ent not only on external conditions, but also on the origi-  et al. 1960). Since grain size plays a major role in deter-
                 nal geometry of the aggregate before deformation.  mining which deformation mechanism will be active, sev-
                                                               eral maps for different grain sizes are usually given.
                 3.14                                            Figure 3.43 shows an example of a deformation  3.14
                 Flow Laws and Deformation Mechanism Maps      mechanism map for quartz, and the way in which it is
                                                               constructed. Parameters that have been used are given
                 In order to establish under which conditions deforma-  in the inset. Using the equations given in Box 3.11, graphs
                 tion mechanisms as described in this chapter are active,  are first made which plot shear stress against tempera-
                 data from experimental deformation are used in combi-  ture at given strain rates for each of the deformation
                 nation with observations on rocks deformed at known  mechanisms (Fig. 3.43a–c). In such graphs, normalised
                 metamorphic conditions. Experimental deformation of  units are plotted. This is done to obtain numbers that are
                 rocks at a range of pressure and temperature conditions  dimensionless since this allows easy comparison of dif-
                 can give us some idea of the activity of deformation, recov-  ferent materials (Box 2.5). For example, homologous tem-
                 ery and recrystallisation processes at specific conditions.  perature T  (T = T / T  where T  is the melting tempera-
                                                                                       m
                                                                          h
                                                                       h
                                                                                m
                 One drawback of experimental work is that geologically  ture of a mineral in K) is used on the horizontal scale
                                                       s  can-
                 realistic strain rates in the order of 10 –12  to 10 –14 –1  instead of absolute temperature; T = 0 at 0 K and T =1
                                                                                         h             h
                 not be reproduced in experiments. Nearly all our data on  at the melting temperature of the mineral. In this way,
                 deformation mechanisms are from experiments at much  deformation behaviour of ice can be compared with that
                 higher strain rate. However, for many deformation mecha-  of steel if both are at the same T  value. Similarly, nor-
                                                                                         h
                 nisms, increase in temperature has an effect similar to a  malised shear stress (σ / µ) is used instead of shear stress.
                 decrease in strain rate. Therefore, extrapolation of experi-  At any point in the graphs of Fig. 3.43a–c, a single strain
                 mental results to geologically realistic strain rates is pos-  rate is defined at a certain stress and temperature if other
                 sible by ‘projection’ of data from experiments carried out  parameters are constant. When these diagrams are com-
                 at higher temperature.                        bined in pairs (Fig. 3.43d,e), each point will be attributed
                   The rheological behaviour of minerals and rocks is  two strain rate values, one for each of the possible defor-
                 usually expressed in flow laws (Poirier 1985; Hirth et al.  mation mechanisms; the mechanism with the highest
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