Page 330 - Modelling in Transport Phenomena A Conceptual Approach
P. 330

310   CHAPTER 8.  STEADY MICROSCOPIC BALANCES WITHOUT GEN.

             Analysis

             System:  Benzene droplet
             The inventory rate equation for mass of  A gives

                    - Rate of  moles of  A out = Rate of accumulation of moles of  A   (1)












             where p:  is the density of  species A in the liquid phase.
                The rate  of  evaporation from the droplet surface, +LA, can be  determined from
             Eq.  (8.5-28).  However,  remember that Eq.  (8.5-28) was  developed  for  a  steady-
             state  case.  For the unsteady problem at hand, the pseudo-steady-state assumption
             implies that Eq.  (8.5-28) holds at any given instant, i.e.,





             Substitution of  Eq.  (3)  into Eq.  (2) and rearrangement gives





             where  R,  is the initial radius of the liquid droplet.  Carrying out the integrations
             in Eq.  (4) yields





             Since
                                        P                 PPt
                                   c=-        and    c*  - -
                                       UT             A-  RT
             Eq.  (5) tamss the Jvrm






             The plot of  R2 versus t is shown below.
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