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332       CHAPTER 9. STEADY MICROSCOPIC BALANCES WITH GEN.

                At  the liquid-air  interface, the jump  momentum balance’  indicates that  the
             normal  and  tangential components of  the  total  stress tensor  are equal  to  each
             other, i.e.,
                                 at x = o   P’  = pA    for all z            (9.1-47)
                                 at x = o   T,”, = 7tz   for all z           (9.1-48)

             Since both PL and PA depend only on z, then
                                           dPL  dPA
                                           -- --                             (9.1-49)
                                            dz     dz
             From Eqs.  (9.1-46) and (9.1-49) one can conclude that
                                           dPL
                                           -
                                            dz   = PAS                       (9.1-50)
             Substitution of Eq. (9.1-50) into Eq.  (9.1-43) gives

                                     -p  s-                                  (9.1-51)
                                        L @v,t
                                               - (PL -PA)  9
             Since pL >> pA, then pL - pA M pL and l3q.  (9.1-51) takes the form

                                                                             (9.1-52)

             This  analysis shows the  reason why  the pressure term  does  not  appear  in  the
             equation of  motion when  a fluid  flows  under  the action of  gravity.  This point
             is usually overlooked in the literature by  simply stating that  “free surface + no
             pressure gradient.”
                For simplicity, superscripts in Eq. (9.1-52) will be dropped for the rest of  the
             analysis with the understanding that properties are those of the liquid.  Therefore,
             the governing equation takes the form


                                                                             (9.1-53)

             Integration of Eq. (9.1-53) twice leads to

                                                                             (9.1-54)

             The boundary conditions are
                                                     dvz
                                         at  x=O     -=O                     (9.1-55)
                                                      dx
                                         at  x=6     vz=O                    (9.1-56)

               ‘For a thorough discussion on jump balances, see Slattery (1999).
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