Page 496 - Modelling in Transport Phenomena A Conceptual Approach
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476    CHAPTER 11.  UNSTEADY MICROSCOPIC BALANCES WITH GEN.

                                                 r
                                             I=-                            (1 1.1-18)
                                                 R
                                                                            (1 1.1-19)
            reduces Eq. (11.1-13)-(11.1-16) to the form


                                                                            (11.1-20)

                                       at  T=O      8=0                     (11.1-21)
                                                   ae
                                      at  E=O      -=0                      (1 1.1-22)
                                                   %
                                       at  t=l  e=O                         (1 1.1-23)

            Since Eq. (11.1-20) is not homogeneous, the solution is proposed in the form
                                     @(T, E) = eOo(0 - et(T, 0              (I 1.1-24)

            in which Boo  is the steady-state solution, i.e.,
                                                                            (11.1-25)


            with the following boundary conditions

                                      at  <=O     de,                       (11.1-26)
                                                  -- -0
                                                   dE
                                      at  t=1  e,=O                         (1 1.1-27)
            Integration of Eq.  (11.1-25) gives

                                                                            (11.1-28)

            The use of  Q. (11.1-26) gives CI = 0.  Integration of  Eq.  (11.1-28) once more
            and the application of  the boundary condition defined by  Eq.  (11.1-27) gives the
            steady-state solution as
                                           e,=i-t2                          (1 1.1-29)
            which is identical with Eq.  (9.1-79).
               The use of Eq. (11.1-29) in Eq.  (11.1-24) gives
                                     e(T, t) = 1 - t2 - Ot(T, t)            (11.1-30)

            Substitution of  Eq. (11.1-30) into Eqs.  (11.1-20)-(11.1-23) leads to the following
            governing equation for  the transient  problem  together  with  the  initial  and  the
            boundarv conditions
                                                                            (11.1-31)
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