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PREFACE TO THE FIRST EDITION ix
“further reading” lists, the policy is to cite papers which are classics in the development
of the subject, together with papers of particular interest concerning recent develop-
ments, and in particular, reviews of the last few years.
It is hoped that this book will not only be useful to those who wish to work with
modern electrochemical ideas in chemistry, physics, biology, materials science, etc.,
but also to those who wish to begin research on electron transfer at interfaces and
associated topics.
The book was written mainly at the Electrochemistry Laboratory in the University
of Pennsylvania, and partly at the Indian Institute of Science in Bangalore. Students
in the Electrochemistry Laboratory at the University of Pennsylvania were kind
enough to give guidance frequently on how they reacted to the clarity of sections
written in various experimental styles and approaches. For the last four years, the
evolving versions of sections of the book have been used as a partial basis for
undergraduate, and some graduate, lectures in electrochemistry in the Chemistry
Department of the University.
The authors’ acknowledgment and thanks must go first to Mr. Ernst Cohn of the
National Aeronautics and Space Administration. Without his frequent stimulation,
including very frank expressions of criticism, the book might well never have emerged
from the Electrochemistry Laboratory.
Thereafter, thanks must go to Professor B. E. Conway, University of Ottawa, who
gave several weeks of his time to making a detailed review of the material. Plentiful
help in editing chapters and effecting revisions designed by the authors was given by
the following: Chapters IV and V, Dr. H. Wroblowa (Pennsylvania); Chapter VI, Dr.
C. Solomons (Pennsylvania) and Dr. T. Emi (Hokkaido); Chapter VII, Dr. E. Gileadi
(Tel-Aviv); Chapters VIII and IX, Prof. A. Despic (Belgrade), Dr. H. Wroblowa, and
Mr. J. Diggle (Pennsylvania); Chapter X, Mr. J. Diggle; Chapter XI, Dr. D. Cipris
(Pennsylvania). Dr. H. Wroblowa has to be particularly thanked for essential contributions
to the composition of the Appendix on the measurement of Volta potential differences.
Constructive reactions to the text were given by Messers. G. Razumney, B. Rubin,
and G. Stoner of the Electrochemistry Laboratory. Advice was often sought and
accepted from Dr. B. Chandrasekaran (Pennsylvania), Dr. S. Srinivasan (New York),
and Mr. R. Rangarajan (Bangalore).
Comments on late drafts of chapters were made by a number of the authors’
colleagues, particularly Dr. W. McCoy (Office of Saline Water), Chapter II; Prof. R.
M. Fuoss (Yale), Chapter III; Prof. R. Stokes (Armidale), Chapter IV; Dr. R. Parsons
(Bristol), Chapter VII; Prof. A. N. Frumkin (Moscow), Chapter VIII; Dr. H. Wrob-
lowa, Chapter X; Prof. R. Staehle (Ohio State), Chapter XI. One of the authors
(A.K.N.R.) wishes to acknowledge his gratitude to the authorities of the Council of
Scientific and Industrial Research, India, and the Indian Institute of Science, Banga-
lore, India, for various facilities, not the least of which were extended leaves of
absence. He wishes also to thank his wife and children for sacrificing many precious
hours which rightfully belonged to them.