Page 257 - Petroleum Geology
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            dustry  at large  to note that geochemical hypotheses  concerning the source
            rocks of some oil fields and provinces are at variance with geological and log-
            ical arguments. Our purpose in  this chapter is to concentrate on the discrep-
            ancies because it is from these that true relationships and processes will most
            convincingly be demonstrated eventually. We  cannot be satisfied until a co-
            herent  geological, geochemical and hydrogeological synthesis for each field
            emerges. We  start on a positive note.  -
              Probably  the most  convincing case in which geological argument concern-
            ing  the source,  migration  and  accumulation  of  significant quantities of  oil
            and gas is not contradicted by geochemical or hydrogeological arguments lies
            in the North American  Silurian reef  province of the Michigan basin, and the
            Devonian reef province of the Western Canada basin.
              There  are  two reasons for stating that the source rock of  reef  accumula-
            tions does not lie in the reef itself:
              (1) The  contemporary  reef  environment  is  one  of  high  energy,  rich in
            oxygen,  with  much  of  the  organic  matter  in  the food chain.  All these 9.re
            considered inimicable to the preservation of large quantities of organic matter.
              (2) In groups of reefs, some contain gas, some contain oil and gas, some
            contain  oil  and  some  only  water.  Groups  of  reefs probably  shared closely
            comparable  environments while they grew, and have since had almost identi-
            cal geological histories, so it seems inconceivable that the variety of petroleum
            content could arise from an internal source.
              GUSSOW’S
                        (1954) hypothesis  of  differential entrapment, which arose from
            his observations in the Western  Canada basin, has since been found to apply
            convincingly to the Michigan basin (Gill, 1979) and to other areas (e.g. West
            Irian:  Trend  Exploration  Technical  Staff,  1973). This  hypothesis  requires
            for those areas where differential entrapment has occurred that the source is
            down-dip from the deepest, gas-filled reef, and that the secondary migration
            path  to the shallowest, oil-bearing reef  extends at least to the deepest. The
            progression from lighter to heavier crudes from the deepest to the shallowest
            oil-bearing reefs may also be a function of the length of the secondary migra-
            tion path (not necessarily exclusively), with the removal of the more water-
            soluble components during migration, as well as any effect of de-gassing.
              These geological observations require for those areas with  differential en-
            trapment that the source of the petroleum is stratigraphically  closely related
            to the  accumulations:  the  stratigraphy  suggests that the source rock is the
            fine-grained mudstones or mark that ouerlie the permeable carrier bed -the
            permeable carbonate “platform”  on which the reefs grew (Fig. 11-1). These
            source rocks accumulated  while the reefs grew, but they accumulated in the
            still, deep water at some distance from the reefs. Generation, migration and
            accumulation could  have begun as soon as the reefs were drowned and closed.
            In  any case, generation and migration  probably took place over a consider-
            able span of  time as subsidence gradually took the source rocks to tempera-
            tures at which generation could begin.
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