Page 84 - Petrology of Sedimentary Rocks
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B.     Late   Syngenetic   (Shallow   Burial).   Cement   develops   while   the  sediment
                        is  buried   anywhere   from   a  few   feet   to  perhaps   several   hundred   feet   or
                        more   beneath   the   sea   floor.   Precipitation   occurs   from   connate
                        (trapped)   sea  water,   which   is  essentially   stationary   or  at  most   moved   a
                        short   distance.

           2.    Epigenetic   Stage

                 A.     Deep   Burial.   Cement   develops   while   the  sediment   is  buried   a  thousand
                        feet   or  much   more   beneath   the  sea  floor,   but   prior   to  any  structural
                       deformation   of  the  beds.   Precipitation   occurs   from   subsurface   water
                       which   may   have   moved   long   distances   through   the   formation   or
                       adjoining   formations,   and  which   may  be  a  mixture   of  fresh   water   with
                        connate   water.   Some   silica   may   be  supplied   by  waters   pressed   out   of
                       shales   on  compaction.   Source   of  silica   can  be  the  Si  liberated   when
                       montmorillonite    changes   to  illite,   or  from   solution   of  buried   opaline
                       skeletons.


                 B.     Post-Structural   Deformation.   Cement   develops   during   or  after   uplift
                       or  structural   deformation   of  the   depositional   basin.   “Deformation”
                       here   includes   anything   from   gentle   warping   to  intense   folding   and
                       faulting;   the  essential   point   is  that   now  sediments   are   no  longer   being
                        laid  down   in  the  same   basin.   Source   of  the  silica   may  be  far-travelled
                       subsurface   waters;   solution   of  detrital   quartz   grains   under   pressure
                       provides   a  small   amount   of   silica   (the   so-called   Riecke   principle,
                       actually   first   described   by  H.  C.  Sorby   in  1863;   see  Sibley   and  Blatt
                        I976   JSP).

                 C.    Hydrothermal.     Occurs   generally   during   or  after   structural   deforma-
                       tion,   from   waters   heated   by  magmatic   activity   and  carrying   in  solution
                       products   sweated   off   from   igneous   bodies.   These   may   penetrate   a
                       formation   and  be  carried   along   with   the  migrating   subsurface   waters.
                 D.    Weathering.    Occurs   when   the  sediment   is  nearing   the  present   ground
                       surface;   silica   may  be  carried   by  ground   (meteoric)   waters.

           For  any  given   formation,   deciding   when   it  became   cemented   with   quartz   is  a  very
     difficult   problem.   Petrographic   work   must   be  supplemented   with   extensive   field   work;
     in  fact   field   work   is  probably   the  best  method   of  attack.   The  microscope   must  be  used
     however   to  determine   how  the  cement   formed   (by  replacement   or  direct   precipitation);
     the  nature   of  diagnostic   inclusions   which   might   indicate   temperature   or  composition   of
     the   precipitating   solutions;   whether   the   cement   has  spread   the   sand   grains   apart   by
     pressure   of  its  growth;   the  relation   of  the  cement   to  joints,   stains,   alteration   or  other
     time   markers.   But  field   work   combined   with   intelligent   sampling   is  generally   required
     to  obtain   the  areal   and  stratigraphic   distribution   of  cement,   which   is  generally   the  key
     to  the   problem.   For   example,   if  a  formation   is  cemented   uniformly   over   tens   of
     thousands   of  square   miles,   the  cement   is  probably   syngenetic,   formed   from   sea  water   at
     the  same   time   as  or  just   after   the  sand   grains   were   being   deposited.   Hydrothermal
     sources   are  rather   easy  to  establish   or  eliminate   by  noting   if  the  formation   is  cemented
     only   in  the   vicinity   of  known   hydrothermal   activity;   widespread   cements   cannot   be
     caused   by  this   process.   Whether   or  not  the  cement   has  formed   on  deep   burial   can  be
     determined   by  reconstructing   the  structural   history   of  the  area   in  which   the  formation
     occurs;   parts   of  the  formation   never   deeply   buried   then   should   lack  cement.   Cements
     quite   frequently   are   related   to   the   structural   geology   of   a  formation;   many   are





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