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342    PETROPHYSICS: RESERVOIR ROCK PROPERTIES



                                                TABLE 5.1A
                       CALCULATION  OF CAPILLARY PRESSURE FOR AIR  DISPLACING WATER FROM A
                                           BEREA SANDSTONE CORE
                                                             S(ave)
                     ~~                   ~~                     ~~               ~
                      1,300                0.30               0.827              4.135
                      1,410                0.40               0.769              4.865
                      1,550                0.50               0.71 1             5.879
                      1,700                0.60               0.653              7.071
                      1,840                0.70               0.595              8.284
                      2,010                0.75               0.566              9.885
                      2,200                0.80               0.538             11.843
                      2,500                0.90               0.480             15.293
                      2,740                1 .oo              0.422             18.370
                      3,120                1.05               0.393             23.818
                      3,810                1.10               0.364             35.518
                      4,510                1.20               0.306             49.769
                      5,690                1.25               0.277             79.219


                      Units of pounds per square inch (psi) were used to determine the three
                    constants (A, B, and C) for Equation 5.44 by the least-squares regression
                    analysis of  the experimental data in order to avoid very large numbers
                    that would result from the use of kPa in these calculations.
                      The values of the constants for Pc(hy) versus S are: A = -25.5296,  B =
                    17.6118, and C = -4.5064. The regression analysis was used once more
                    to obtain the constants for Pc(hy) versus Si, which differ only with respect
                    to the first constant (A);  the second set of constants is: A2  = -24.5296,
                    B2  = 17.6118, and C2 = -4.5064.


             PORE SIZE  DISTRIBUTION


                      An approximate pore size distribution of rocks can be obtained from
                    capillary pressure curves if one of the fluid phases is non-wetting. If one
                    phase is non-wetting, cos 8 in Equation 5.11 is assumed to be equal to
                    1.0 at all saturations. The capillary pressure is then a function of only the
                    interfacial tension and the radius of the pore. Equation 5.1 1 is based on
                    uniform capillary tubes; however, a rock is composed of interconnected
                    capillaries with varying pore throat sizes and pore volumes. The capillary
                    pressure required to invade a given pore is a function of the size of pore
                    throat. Although determination of  the pore throat  size distribution of
                    rocks based on capillary pressure curves is only an approximation, the
                    distribution is an important parameter for analysis of many fluid transport
                    properties of porous media [23].
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