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50     PETROPHYSICS: RESERVOIR ROCK PROPERTIES



                      After  leaving  the  source  rock,  the  hydrocarbons  migrate  upward
                    through  permeable  beds  until  they  reach  a sealed  hydrocarbon  trap
                    where  accumulation  occurs  forming  a  hydrocarbon  reservoir.  This
                    process has been  called the secondary migration,  which is governed
                    principally by buoyancy and hydrodynamic flow [9].

             PRIMARY MIGRATION


                      The geochemical evidence of  the generation for petroleum shows
                    that  hydrocarbons  do  not  generally  originate  in  the  structural  and
                    stratigraphic traps in which they are found. The petroleum reservoirs
                    are porous, permeable geologic structures, whereas the source rocks
                    have been identified as compacted, impermeable shales. Inasmuch as
                    the source rocks are impermeable, the method of expulsion of oil from
                    the shales where it is generated is not obvious. Considerable data on the
                    expulsion of water from shale during compaction show that most of the
                    pore water is squeezed out during burial before the temperature required
                    for the generation of petroleum is attained (Figure 2.8).
                      Compaction  of  sediments  begins  as  soon  as  the  sediments  begin
                    to  accumulate.  During  original accumulation,  the loose, fine-grained
                    sediments contain more than 50% water.  As they are buried deeper,
                    due to subsidence and continued deposition of  sediments on top, the
                    interstitial water  from  the deeper sediments is expelled,  resulting in
                    a decrease in porosity and an increase in density. The material acquires
                    cohesive strength as the grains are pressed together tightly. Chemical
                    changes  occurring in  the  interstitial fluids produce  precipitates that
                    cement the grains into an even more cohesive formation.
                      The  major  oil generation occurs  well  below  the  depth  at  which
                    compaction of  the  shale  is  almost  complete.  Consequently,  the  dis-
                    placement of  oil from most source rocks could not have taken place
                    when  the shales were  being  compacted  [6]. Expulsion of  oil during
                    compaction may have taken place in a few isolated cases where rapid
                    burial resulted in the development of  abnormally high pore pressures
                    or zones of  abnormally high  temperatures at  shallow depths.  Barker
                    contends that petroleum may be expelled from the top and bottom of
                    source rocks due to the pressure gradient that develops during deep
                    burial  1161. After  expulsion  of  the pore water,  petroleum formed in
                    the  organically rich  shale  may  form  a  continuous phase  and  move
                    along a network of fine, thread-like channels under the applied physical
                    stress 1131.
                      Some  clay  minerals  (smectites  in  general)  contain  bound  water
                    within the lattice structure of  the clay particles.  This bound water is
                    expelled when  the  smectites are  transformed to illite, which  begins
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