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Section 2 revised 11/00/bc  1/17/01  12:04 PM  Page 231








                                                                                  2.5.6
                                                            Drilling Fluids Program  [      ]



                       polymer mud. A field in northern central Siberia increased production
                       per well from 40 tons per day to above 120 tons per day. The change
                       was that, instead of the previously used mud with dispersants (lignin
                       liquors such as cmad, kssb) and poor control of solids, a 3% KCl poly-
                       mer system was used.
                           Another factor to consider is pH. High pH might also cause dis-
                       persion of interstitial clays. It may also cause emulsions dependent on
                       the crude in the reservoir.
                           The occurrence of precipitates should be avoided. Potential to gen-
                       erate precipitate scales because of reaction of filtrate with connate
                       water should be investigated. It should also be remembered that in
                       some cases scaling can occur due to changes in wellbore pressure. If
                       there is a possibility that scaling may occur, a scaling tendency for the
                       fluid planned to be used should be made against the chemistry of the
                       connate water. It should take into consideration chemical concentra-
                       tions as well as temperatures and pressures. Most major mud compa-
                       nies can do this as well as operators and independent laboratories.
                       Without going into complete detail on scaling, an idea of the potential
                       causes of scaling can be derived from the type of scales experienced in
                       the oilfield. In many cases (but not all) one ion will come from the fil-
                       trate and another from the connate water. The reader is directed to fur-
                       ther reading in production operations manuals for further detail. Types
                       of scales are:


                           Carbonate scale; the carbonate or bicarbonate ion with the calcium
                           ion
                           Gypsum or anhydrite scale; the sulfate ion with the calcium ion
                           Barium or strontium scale; the barium or strontium ion with the
                           sulfate ion
                           Iron scales; ferric or ferrous ions, usually as corrosion by-products
                           with oxygen or sulfides
                           Sodium chloride precipitates; changes in pressure and temperature

                           Carbonate ion or sulfate ion can cause scaling if present in suffi-
                       cient or certain quantities in the connate water (or filtrate). Often min-
                       imizing the concentration of divalent cations such as calcium is
                       enough to avoid this type of scaling. The use of monovalent brines
                       such as sodium chloride, sodium bromide instead of calcium chloride,
                       and calcium bromide might be considered.


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