Page 24 - Principles of Catalyst Development
P. 24

10                                                       CHAPTER  1





                       4  -
                     E
                     o                ,tablets
                     - 3
                    CL                 extrudates
                    <l
                                       /' rings
                    0::
                    o  2
                    I-                       lobes
                    u
                    <l:
                       0 L                                          I
                    W
                    0::



                         0               1.0              2.0
                                PARTICLE  DIAMETER,  em

                       Figure  1.3.  Typical  reactor pressure drop  for  catalyst particles.





           100 - 3,000 aIm
                ~                      mesapores   .~
                                 ~ r<  15nm
                                  ;'(
                                  ~~ ~            "0          -- low  pressure
                                                  ~
                                  rfJ~            ....        ---- high  pressure
                                Particle          o
                                                  <II
                                                  ~
                                .-Imacropores     o
                                                  a.
                                WI  r>15nm        ....
                                                  o
                                                  ....
                                                  '"
                                                  .Q
                                 Pellet           E
                                                  ::l
                                                  Z
                                                       10     10
                                                            pore  radius, r,  nm
               (a)                ( b)                           (e)
            Figure  1.4.  Pore structure development in  catalyst pellets.  (a)  Pellet production. (b) Origin of
            pores.  (c)  Pore size  distribution.
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