Page 250 - Radiochemistry and nuclear chemistry
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234                  Radiochemistry and Nuclear Chemistry


                        .lO        III!11                  IIIIIII
                        .09      ,,o~.~. ~..m ,~o,, ~ f  ~~
                        .08                      //
                        .07
                        .06
                                              /
                    F'OV) .os
                        .04                  /   F
                                           /                   \
                        .03                                   k
                        .02                r
                                         ./                      \
                         .01
                        ,00
                          0   2   4   6   8   10  12  14  16  18  20  22  24  26  28  30  32  34  36  38  40
                                                     N
                        FIG.  8.23.  Poisson  (smooth) and  Gaussian (dashed  line) distributions  for/9  =  20.

              interval  for  the  same  sample.  It  is  necessary,  when  counting  a  sample,  to  be  able  to
              calculate the probability  that the recorded count  rate is within certain limits of the true (or
              average)  count  rate.
                The  binomial  distribution  law  correctly  expresses  this  probability,  but  it  is  common
              practice to use either the Poisson  distribution or the normal Gaussian distribution  functions
              since  both  approximate  the  first  but  are  much  simpler  to  use.  If  the  average  number  of
              counts  is high  (above  100)  the Gaussian  function  may be  used with  no  appreciable  error.
              The probability  for observing  a  measured  value of total  count  N  is

                                       P(N)  =  (27r/9)- '~ e-"~(~'-~0~/tr         (8.17)




                        2.6
                        2.4  ,~
                        2.2\
                             \
                        2.0
                        1.8    k  .
                               \,.
                        1.6      \
                      ~J.4          \
                        ].2           %.
                        J.O
                        0.8
                        0.6
                        0.4
                        0.2
                        0.0
                               0.1  0.2  0.3  0.4  0.5  0.6  0.7  0.8  0.9  1.0
                                         Probobility  of  error  )  K
                       FIG.  8.24.  The  probability that an error will be greater than Ko  for different K-values.
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