Page 286 - Refining Biomass Residues for Sustainable Energy and Bioproducts
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254                     Refining Biomass Residues for Sustainable Energy and Bioproducts


         12.53 g/L in 1 L parallel fermenter with a productivity of 0.32 and 0.13 g/L/h,
         respectively.
           Pentose-rich acid-pretreated liquor from rice straw as a cosubstrate for 1,3-pro-
         panediol production by Klebsiella pneumoniae PD41 was reported by Vivek et al.
         (2018). The study revealed that an addition of acid pretreatment liquor (0.5% v/v)
         as a cosubstrate resulted in the improved production of 1,3-propanediol (20.88 g/L)
         with a productivity of 0.87 g/L/h.
           Cao et al. (2015) reported 1,2,4-butanetriol production from renewable biomass.
         In this study a recombinant strain capable of pentose utilization was used for the
         production of 1,2,4-butanetriol. The study revealed that under optimized conditions
         the engineered strain can efficiently convert xylose to 1,2,4-butanetriol. A maxi-
         mum yield of 1,2,4-butanetriol is 3.92 g/L from 20 g/L of xylose with a conversion
         efficiency of 27.7%.
           Potential of oil palm front hydrolyzate for 2,3-butanediol production by
         Enterobacter cloacae SG1 was evaluated by Hazeena et al. (2016). Nondetoxified
         oil palm hydrolyzate was used as the sole carbon source which resulted in a produc-
         tivity of 7.67 g/L. With glucose as a carbon source the strain produced 14.67 g/L of
         2,3-butanediol. Fine tuning of various process parameters affecting 2,3-butanediol
         production can improve the yield.


         11.3   Lignin valorization

         Lignin is the second abundant polymer and a highly branched macromolecule that
         finds applications in biological, pharmaceutical, pulping, biosorption (Ge and Li,
         2018), and polymer industries. Lignin can be used for the controlled release of her-
         bicides and pesticides. It is used for the controlled release of urea that is highly
         water soluble and leads to excess nitrogen level in the soil (Mulder et al., 2011).
         Since urea got incorporated in the lignin layer, it resulted in a coating with low
         water resistance. The study revealed that coating with lignin is an economically via-
         ble strategy for a controlled release of urea. Lignosulfates are widely used as a
         binding and dispersing agent (Stewart, 2008).


         11.4   Conclusion and future perspectives

         Agroresidues serve as a potential feedstock for the production of different value-added
         products. Even though several R&D activities are going on throughout the world and
         the technology for the conversion of lignocellulosic biomass to various products is
         already proved, still an economically viable process is lacking. Hence fine tuning at
         each unit operations as well as development of suitable consortium or genetically modi-
         fied strains is required for an improved product yield and process efficiency.
         Development of engineered strains or consortium that can grow on mixed agroresidues
         and in the presence of inhibitors will reduce the overall process economics. Adopting a
         biorefinery approach may lead this to a reality in the near future.
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