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Petrophysics-Flow Functions and Parameters  69

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                               0.1  O.Z  0.3  0.4  0.5  0.6  0.7  0.6
                                   WATER  SATURATION  (FRACTION)
             Figure  4-1.  Effect  of  pore  plugging  by  clay  particles  on  capillary  pressure
             (Donaldson,  ©1985  SPE; reprinted  by permission  of the  Society  of  Petroleum
             Engineers).




             Jerauld  and Rathmell (1997)  show that  the Amott-Harvey wettability index
             correlates  linearly  and  increases  with  the  initial  saturation  for  Prudhoe.
             Ertekin  and  Watson  (1991)  show  that  the  wettability  index  correlates
             linearly  and  decreases  with the average  pore-throat  length. Figure 4-2  by
             Leontaritis  et  al.  (1992)  describes  the  alteration  of  wettability towards  oil-
             wet  by  adsorption  of organic matters,  such  as asphaltenes.  Figure  4-3  by
             Yan  et  al.  (1997)  clearly  indicates  that  the  wettability index  decreases  as
             the  adsorption  of  asphaltenes  progresses.
               Durand  and  Rosenberg  (1998)  have  determined  by  cryo-scanning
             electron  microscopy  that the bulk or  apparent  wettability of  clay-bearing
             formations  is  significantly  influenced by  the  type,  morphology, quantity,
             and  location  of  the  clay  minerals,  and  the  trapment  of  fluids  in  the  pore
             space.  They  explain  that,  when  water-wet  kaolinite  and  platy  illite  are
             aged  in  oil,  these  minerals  absorb  some  oil  components  to  become  oil-
             wet. Whereas,  the fibrous illite  does  not  show  any  affinity  toward oil and
             it  remains  water-wet. However,  even  a  small  amount of  kaolinite  of platy
             illite can make  a clay-bearing  sandstone oil-wet after  aging with oil.  Once
             transformed  into  an oil-wet  system,  as depicted  by Durand and  Rosenberg
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