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                                                     RPS: PSP0007 - Science-at-Nanoscale
                   June 9, 2009
                              Brief Review of Quantum Mechanics
                          32
                                          Blackbody Radiation
                                   3.1.1
                                   Blackbody radiation refers to electromagnetic (EM) radiation
                                   emitted from a small hole in a cavity with walls maintained at
                                   a certain temperature. A schematic of the experiment is shown in
                                   Fig. 3.1(a). Atoms comprising the wall are continuously emitting
                                   electromagnetic radiation as well as absorbing radiation emitted
                                   by other atoms of the wall. Thus the cavity is filled with electro-
                                   magnetic radiation. At equilibrium, the amount of energy emitted
                                   is equal to the amount of energy absorbed. And the energy den-
                                   sity of the EM field is constant. A small hole in the cavity allows
                                   some EM radiation to escape from the cavity and be detected dur-
                                   ing the experiment. The resultant monochromatic energy den-
                                   sity of the blackbody radiation as a function of the wavelength
                                   typically obtained during the experiment is shown in Fig. 3.1(b).
                                   It can be seen from the plot that for a certain temperature, the
                                   energy density shows a pronounced maximum at a certain wave-
                                   length known as the Wien’s wavelength. The Wien’s wavelength
                                   decreases as the temperature increases. This explains the change
                                   in color of a radiating object as its temperature changes.
                                     According to classical theory, the radiated intensity (I) of the
                                   emitted radiation is given by
                                                                    1
                                                                                         (3.1)
                                                          I(λ, T) ∝
                                                                     4
                                                                    λ
                                   where λ is the wavelength of the emitted radiation.
                                   classically the radiated intensity of electromagnetic radiation is
                                                                           Classical Theory Hence  ch03
                                             Blackbody Radiator               Experimental Data
                                                                 Intensity
                                      Detector
                                                                         Wavelength
                                                    (a)                     (b)
                                   Figure 3.1.  (a) Schematic of the Blackbody radiation experiment and (b)
                                   a plot of the energy density of the blackbody radiation at a certain tem-
                                   perature together with the theoretical prediction from classical theory.
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