Page 307 - Tandem Techniques
P. 307

Page 291

            moving ribbon devices with pre-concentrating techniques, in a similar manner to that of Scott et al., but
            were rather unsuccessful. Their final system was rather crude but, nevertheless, an effective transport
            system that utilized the principle of the rotating disk. Their final model took the form of a carousel of
            cups containing potassium chloride.



























                                                          Figure 8.1
                                                Carousel Transport for On-line IR
                                                Monitoring of LC Column Eluents

            A diagram of their carousel is shown in Figure 8.1. The carousel was very similar to a fraction collector,
            and consequently the device might be considered more like an off-line auto fraction collector than an
            in-line interface. In fact, all transport interfaces might be deemed automated offline monitoring device,
            depending on the speed of the transport process. Fast transport, as with the wire or belt transport
            interface used in LC/MS, gives the impression of being an in-line devices. Conversely, the carousel
            transport interface described here, being relatively slow, appears more like an automated off-line IR
            sampler.

            The LC/IR interface carousel had 32 cups, each fitted with a fine mesh screen and containing potassium
            chloride powder. The position of the
   302   303   304   305   306   307   308   309   310   311   312