Page 187 - Thermodynamics of Biochemical Reactions

Glossary 187

further transformed Gibbs energy of a system at k Boltzmann constant (J K I)
G "
specified 7; P, ionic strength, and concentrations of K equilibrium constant written in terms of
one or more species and one or more reactants (J) concentrations of species at specified 7: P. and ionic
standard Gibbs energy of formation of species j at strength
specified 7; P, and ionic strength (J mol-') K' apparent equilibrium constant written in terms of
Gibbs energy of formation of speciesj at specified 7; concentrations of reactants (sums of species) at
P, and ionic strength (J mol-I) specified 7; P, ionic strength and concentrations of
4 G Gibbs energy of chemical reaction (J mol- ') one or more species
A,G' standard Gibbs energy of chemical reaction (J K " apparent equilibrium constant written in terms of
moI - ') concentrations of pseudoisomer groups (sums
A, G~:() standard transformed Gibbs energy of formation of of reactants) at specified 7; P, ionic strength, and
reactant i at specified 7; P, ionic strength, and concentrations of one or more species and one
specified concentrations of one or more species (J or more reactants
mol- I) Henry's law constant
A~G,''' standard further transformed Gibbs energy of apparent Henry's law constant at a specified pH
formation of a pseudoisomer group of reactants at acid dissociation constant
specified 7; P, ionic strength, and specified Khlp dissociation constant of a magnesium complex ion
concentrations of one or more species and one or L elongation (m)
more reactants (J mol-') 111 mass (kg)
ArG' transformed Gibbs energy of a biochemical reaction in transformation matrix
(J mol-l) m magnetic moment of a system (J T-')
A,G'" standard transformed Gibbs energy of reaction at a 117 magnitude of the magnetic moment of a system (J
specified concentration of a species (J mol-I) r')
A,G" further transformed Gibbs energy of reaction at molar mass of species i (kg mo1-l)
specified concentrations of one or more reactants (J total amount in a system (mol)
mol- ') amount of B bound in the system (mol)
standard further transformed Gibbs energy of amount of species i (mol)
reaction at specified concentrations of one or more set of amounts of species in a system (mol)
reactants (J mol-') amount of reactant i (sum of species) (mol)
A, Gi"" standard further transformed Gibbs energy of amount of pseudoisomer group i (sum of reactants)
formation of reactant i at specified concentrations (moll
of one or more reactants (J mol- j PIci amount of component i (mol)
h Planck's constant 'ci amount of apparent component i at specified
H enthalpy of a system at specified 7; P, and ionic concentrations of one or more species (mol)
strength (J) "ci amount of apparent component i at specified
H' transformed enthalpy of a system at specified 7; P, concentrations of one or more species and one or
ionic strength, and concentrations of one or more reactants (mol)
more species (J) It column vector of amounts of species (N x 1) (molj
further transformed enthalpy of a system at n' column vector of amounts of reactants (sum of
specified 7; P, ionic strength, and concentrations of species) (N' x I) (mol)
one or more species and one or more reactants (J) n" column vector of amounts of pseudoisomer groups
molar enthalpy of species j (J mol-') of reactants (N"x 1) (mol)
enthalpy change in a calorimetric experiment (J column vector of amounts of components (C x I)
mol- I) (ma
standard enthalpy of reaction (J mol- ') column vector of amounts of noncomponents
standard enthalpy of formation of species ,j (J ((N C) x 1) (mol)
~
mol - I) column vector of amounts of apparent components
molar transformed enthalpy of specics ,i (J mol- I) at specified concentrations of one or more species
molar transformed enthalpy of reactant i (J mol-I) (C' x 1) (mol)
standard transformed enthalpy of reaction at a column vector of amounts of apparent components
specified concentration of a species (J mol- I) at specified concentrations of one or more specics
ArH' transformed enthalpy of reaction at a specified and one or more reactants (C" x 1) (mol)
concentration of a species (J mol- I) N number of molecules in a system
A,. H,:' standard transformed enthalpy of formation of N, number of different kinds of species in a system
reactant i at a specified concentration of a species (J "4 Avogadro constant (mol- j
moI ') N' number of different reactants (sums of species) in a
transformed enthalpy of formation of i at a specified system
concentration of a species (J mol- I) N I' number of different pseudoisomer groups of
mole fraction-weighted standard transformed reactants in a system
enthalpy of formation of reactant i at a specified number of isomers in an isomer group or
concentration of a species (J mol-') pseudoisomers in a pseudoisomer group
I ionic strength (mol L I) j) number of hydrogen atoms in species j