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§13.6  Fourier Analysis  of  Energy  Transport in Tube Flow at Large  Prandtl Numbers  419

                for  the Fourier-transformed  temperature  @(Y,  0, z, v). The transformed  boundary  condi-
                tions are

                Inlet  condition:  at z  =  0,  0(^0,2, v) = 0  for У > 0           (13.6-16)
                 Wall  condition:  at Y  =  0,      v) =       forO <  z  < L       (13.6-17)
                 Here again,  the unit impulse  function  8{v) appears  as  the Fourier transform  of  the  func-
                 tion g(t)  = 1 in the long-duration  limit.
                    Two  types  of  contributions  appear  in  Eq.  13.6-15:  real-valued  zero-frequency  im-
                pulses  8{v) from  functions  and products independent of  t, and complex-valued  functions
                of  v  from  time-dependent product  terms.  We  consider  these  two  types  of  contributions
                 separately  here, thus decoupling  Eq. 13.6-15 into two  equations.
                    We  begin  with  the  zero-frequency  impulse  terms.  In  addition  to  the  explicit  8(v)
                 terms  of  Eq.  13.6-15,  implicit  impulses  arise  in the convolution  terms  from  synchronous
                 oscillations  of  velocity  and  temperature, giving  rise  to  the  turbulent  energy  flux  q (f)  =
                pC v'T'  discussed  in §13.2. The coefficients  of  all the impulse  terms must be proportional
                   p
                 functions  of  a,  in  order  that the dominant terms  at  each  point  remain  balanced  (i.e., of
                 comparable  size) as  a  —»  0. Therefore,  the  coefficient  к  of  the convective  impulse  terms,
                including  those  from  synchronous  fluctuations,  must  be  proportional  to  the  coefficient
                                                          1/3
                а/к 2  of  the conductive impulse  term, giving к  ос а ,  or
                                                 к  = Pr"  1/3 D                    (13.6-18)
                 for the dependence of the average thermal boundary layer  thickness on the Prandtl number.
                    The remaining  terms  in  Eq.  13.6-15 describe  the turbulent  temperature  fluctuations.
                 They  include  the accumulation  term 2mv®'  and  the remaining  convection  and conduc-
                 tion  terms. The  coefficients  of  all  these  terms  (including  liriv  in  the leading  term)  must
                be proportional functions  of  a  in order  that these terms likewise remain balanced  as a  —»
                 0. This reasoning  confirms  Eq. 13.6-18 and gives the further  relation  v  ос к, or

                                              ^ o c ! c  P                          (13.6-19)
                                              (v )
                                               z
                 for  the  frequency  bandwidth  A^  of  the  temperature  fluctuations.  Consequently,  the
                                    1/:
                 stretched  frequency  Pr V  and  stretched  time Pr~ £ are  natural variables  for  reporting
                                                           1/3
                 Fourier  analyses  of  turbulent  forced  convection.  Shaw  and  Hanratty 4  reported  turbu-
                 lence spectra  for  their mass transfer experiments analogously, in terms of  a stretched  fre-
                 quency  variable proportional  to  Sc 1/3  v (here  Sc  =  fx/p4t AB  is  the  Schmidt  number,  the
                 mass transfer analog of the Prandtl number, which contains the binary diffusivity  4b AB, to
                 be introduced in Chapter  16).
                    Thus  far  we  have considered  only  the  leading  term  of  a  Taylor expansion  in  к  for
                 each  term  in  the  energy  equations.  More  accurate  results  are  obtainable  by  continuing
                                                                     1/3
                 the  Taylor  expansions  to higher  powers  of  к, and  thus  of  Pr" D.  The resulting  formal
                 solution  is a perturbation  expansion
                                                1/3
                                                                 1/3
                                 0  -  © (Y, в, z, Pr i/)  + K@W,  0, z, Pr ^)  +  •  • •  (13.6-20)
                                       0
                 for  the distribution  of the  fluctuating  temperature over  position and frequency  in a given
                 velocity  field.   _
                    The expansion  for  T (the long-time average  of the temperature) corresponding  to Eq.
                 13.6-20 is obtained  from  the zero-frequency  part  of  0,
                                       0  = 0 (У,  в, z)  + к©!(У, 0, z)  +  •  •  •  (13.6-21)
                                            О

                     D. A. Shaw  and  T. J. Hanratty, AIChE  Journal, 23,160-169 (1977); D. A. Shaw  and  T. J. Hanratty,
                    4
                 AIChE  Journal, 23, 28-37  (1977).
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