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52  Chapter 2  Shell Momentum Balances and Velocity  Distributions in Laminar Flow

                              The results  of  this section are only as good  as the postulates  introduced at the begin-
                           ning  of  the section—namely,  that v  =  v (r)  and  p  = p(z). Experiments  have  shown  that
                                                        z    z
                           these  postulates  are  in  fact  realized  for  Reynolds  numbers up  to about  2100;  above  that
                           value,  the  flow  will  be  turbulent  if  there  are  any  appreciable  disturbances  in  the  sys-
                           tem—that  is, wall  roughness  or  vibrations.  3  For circular  tubes  the  Reynolds  number  is
                           defined  by  Re = D{v )p/ ц, where  D = 2R is the tube diameter.
                                            z
                              We  now  summarize  all  the assumptions  that  were  made  in  obtaining  the  Hagen-
                           Poiseuille equation.
                              (a)  The flow is laminar; that is, Re must be less than about  2100.
                              (b)  The density  is constant ("incompressible  flow").
                               (c)  The flow is  "steady"  (i.e., it does not change with time).
                              (d)  The  fluid  is Newtonian (Eq. 2.3-14 is  valid).
                              (e)  End effects  are neglected. Actually  an "entrance length,"  after  the tube entrance,
                                  of  the order  of  L  = 0.035D  Re, is needed  for  the buildup  to the parabolic  profile.
                                               e
                                  If  the section  of  pipe  of  interest  includes  the entrance region,  a correction must
                                  be  applied. 4  The fractional  correction  in the pressure  difference  or  mass  rate  of
                                  flow never  exceeds  LJLii  L>  L .
                                                             e
                               (f)  The  fluid  behaves  as  a continuum—this assumption  is  valid,  except  for  very  di-
                                  lute gases or very narrow capillary  tubes, in which  the molecular mean free path
                                  is comparable to the tube diameter (the "slip flow region")  or much greater than
                                  the tube diameter (the "Knudsen flow" or "free  molecule  flow"  regime).  5
                              (g)  There is  no slip at the wall, so that B.C. 2 is valid;  this is an excellent  assumption
                                  for  pure  fluids  under the conditions assumed  in  (f). See Problem  2B.9  for  a  dis-
                                  cussion  of wall  slip.

      EXAMPLE 2.3-1        Glycerine (CH OH • CHOH • CH OH) at 26.5°C is flowing through a horizontal tube 1 ft  long
                                                       2
                                      2
                           and  with  0.1  in. inside  diameter.  For a pressure  drop  of  40 psi,  the volume flow rate w/p  is
     Determination  of     0.00398 ftVmin.  The density  of glycerine  at 26.5°C is  1.261  g/cm .  From the flow data, find  the
                                                                             3
     Viscosity  from       viscosity  of glycerine  in centipoises and in Pa •  s.
     Capillary  Flow  Data
                           SOLUTION
                           From the Hagen-Poiseuille equation (Eq. 2.3-21), we  find


                                              S(w/p)L
                                                                      2
                                              /  1ЬЛ/           dyn/cm \/        i   V
                                                               4
                                            тг  40 —-  6.8947 X 10  —    0.05 in. X  -±-  Л ft
                                              V  in.VV          lty/in. 2  Д     12 m./
                                                                    1  min \
                                                      8  0.00398 A  ,.   , 1(1 ft)
                                                       \      min  60  s  /
                                           =  4.92 g/cm  • s  = 492 cp = 0.492 Pa •  s         (2.3-23)


                              3  A. A. Draad  [Doctoral Dissertation, Technical University  of Delft  (1996)] in a carefully  controlled
                           experiment, attained laminar flow up to Re = 60,000. He also studied the nonparabolic velocity  profile
                           induced by the earth's rotation (through the Coriolis effect).  See also A. A. Draad and F. Т.  М.
                           Nieuwstadt, /. Fluid. Mech.,  361, 207-308 (1998).
                              4
                                J. H. Perry, Chemical Engineers Handbook, McGraw-Hill, New York, 3rd edition  (1950), pp. 388-389;
                           W. M. Kays and A. L. London, Compact Heat Exchangers, McGraw-Hill, New York (1958), p. 49.
                              5
                                Martin Hans Christian Knudsen  (1871-1949), professor  of physics at the University of
                           Copenhagen, did key experiments on the behavior  of very dilute gases. The lectures he gave at the
                           University  of Glasgow were published as M. Knudsen, The Kinetic Theory of Gases, Methuen, London
                           (1934); G. N. Patterson, Molecular Flow of Gases, Wiley, New York (1956). See also J. H. Ferziger and H. G.
                           Kaper, Mathematical Theory of Transport Processes in Gases, North-Holland, Amsterdam  (1972), Chapter 15.
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