Page 103 - Volcano and Geothermal Tourism
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80     The Americas



               Hydrogen chloride/hydrochloric acid         from tephra have been documented on Mt Semeru
               Another  volcanic  gas  posing  potential  health   in Indonesia and on Galeras volcano in Colombia
               hazards  for  tourists  is  chlorine.  Chlorine  gas  is   (Baxter and Gresham, 1993; Thouret et al, 2007).
               emitted from volcanoes in the form of hydrogen   In the incident on Galeras, three tourists and six
               chloride  and  hydrochloric  acid  (HCl)  (USGS,   volcanologists were killed while visiting the caldera
               2009a). Exposure to HCl can irritate eyes, mucous   of  the  volcano  when  a  small  eruption  occurred
               membranes  and  the  skin.  It  can  further  induce   without  warning. The  victims  were  pelted  with
               coughing,  burning  of  the  throat  and  a  choking   volcanic bombs >1m in diameter for approximately
               sensation  (Stephenson  et  al,  1991).  Exposure  to   15  minutes  and  sustained  devastating  head  and
               concentrations over 35ppm will irritate the nose,   chest  injuries  along  with  other  impact  injuries
               throat and larynx after short exposure. However,   (Baxter and Gresham, 1993). Volcanic bombs from
               exposure to concentrations >100ppm can result in   this small eruption were found 1km beyond the
               acute  laryngeal  spasm  or  pulmonary  edema   rim of the caldera (Baxter and Gresham, 1993).
               (Stephenson  et  al,  1991).  Recently  it  has  been   Aside from impact injuries, tephra can cause
               noted  that  when  active  lava  in  coastal  regions   health  problems  through  inhalation  and  contact
               flows  into  seawater,  the  results  produce  a  dense   with the skin and eyes. For example, newly fallen
               HCl  mist  that  is  referred  to  as  volcanic  laze   volcanic ash can have acid coatings and be very
               (Heggie et al, 2009). This process occurs when the   abrasive to the skin (Hansell et al, 2006). If inhaled,
               lava  entering  the  ocean  rapidly  boils,  vaporizes   fine  ash  particles  can  cause  respiratory  irritation
               seawater, and produces a white plume containing   and chest discomfort as well as corneal abrasions
               a mixture of HCl and concentrated seawater that   and conjunctivitis.
               is a brine with a salinity about 2.3 times that of   Moreover,  acute  short-term  conditions  such
               seawater and a pH of 1.5–2.0 (Heggie et al, 2009).   as  nasal  irritation  and  dry  coughing  can  occur.
               Table 5.2 displays the seawater chloride reactions   For  tourists  with  asthma  or  other  respiratory
               that produce HCl. Exposure to this dense volcanic   conditions, ash can cause the lining of the airways
               laze is known to have caused the death of tourists   to  produce  more  secretions  which  can  easily
               in Hawai‘i (Heggie et al, 2009).            result  in  more  severe  concerns. The  severity  of
                                                           any such incident will naturally be influenced by
                                                           duration  of  exposure  and  the  presence  of
               Tephra and ash                              crystalline  silica  and  any  volcanic  gases  mixed
               Tephra is a general term describing fragments of   with the ash. Long-term exposure to crystalline
               volcanic rock and lava that are blasted into the air   silica can result in silicosis and conditions such as
               by explosions or carried upward by hot gases and   chronic  obstructive  pulmonary  disease  (COPD)
               lava  fountains  (USGS Volcano  Hazards  Program,   (Hansell et al, 2006).
               2009a). Tephra fragments are classified by size with   Heavy  or  frequent  amounts  of  volcanic  ash
               fragments  <2mm  in  diameter  labelled  as  ash.   pose  an  additional  threat  to  the  structural
               Tephra fragments that are between 2 and 64mm in   capabilities of tourist facilities such as hotels and
               diameter are called volcanic cinders or lapilli, and   ski  lodges.  Such  conditions  from  volcanoes  like
               when  >64mm  in  diameter  are  called  volcanic   Japan’s Mt Usu have had considerable impact on
               bombs or volcanic blocks. Tourist fatalities resulting   the hot-spring resort town of Toyako-Onsen on
                                                           the island of Hokkaido (Hirose, 1982). Moreover,
                                                           another major concern about volcanic ash is the
               Table 5.2  Seawater chloride reactions that produce HCl  threat  it  poses  to  aviation  and  tourist  transport
                                                           operations.  For  example,  visibility  is  greatly
               MgCl  (sea salt) + H O (steam) = MgO (periclase) + 2 HCl (HCl gas)
                  2        2                               reduced during ash falls, and roads, highways and
               2 NaCl (sea salt) + H O (steam) = Na O (sodium oxide) + 2 HCl  airport  runways  become  slippery  or  impassable
                            2         2
                                                           when ground ash becomes wet.
               CaCl  (sea salt) + H O (steam) = CaO (lime) + 2 HCL (HCl gas)
                  2        2                                  Moreover, volcanic ash particles can remain in
               Source: USGS Volcano Hazards Program, 2009  the atmosphere for years and be spread globally by






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