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CHAPTER 5


            Hybrid CO EOR Using Low-Salinity and
                                   2
            Smart Waterflood




            ABSTRACT                                      commercial CO 2 EOR projects. The CO 2 EOR can be
            The CO 2 injection is the widely used enhanced oil  applied with various designs (Jarrell, Fox, Stein, &
            recovery (EOR) method because of economics and  Webb, 2002): (1) continuous CO 2 gas injection
                                                          (CGI), (2) continuous CO 2 injection followed with
            recovery efficiency. Although miscible/immiscible CO 2
            injections mainly enhance the displacement efficiency  water, (3) conventional water-alternating gas (WAG)
            employing a number of advantages, the CO 2 injection  followed with water, (4) tapered WAG, and (5) WAG
            has an inherent unfavorable mobility ratio because of  followed gas. Using the water, the CO 2 EOR can
            low-viscous CO 2 gas. To support the EOR potential of  improve the sweep efficiency as well as displacement
            CO 2 injection, auxiliary water injection is developed  efficiency. Recently, the usage of low-salinity water or
            to cooperate in CO 2 injection. The coapplication of  smart water rather than conventional water into the
            water and CO 2 injections enhances displacement  CO 2 EOR has been proposed to introduce the synergy.
            efficiency as well as sweep efficiency improving  The applications of hybrid low salinityeaugmented
            the mobility ratio. Recently, the use of low-salinity  CO 2 EOR (LS-CO 2 EOR) are discussed in this chapter.
            water rather than conventional high-salinity water in  Before the discussion of recent investigations of the
            coinjections of water and CO 2 is proposed as low  LS-CO 2 EOR, the important aspects of CO 2 injection
            salinityeaugmented CO 2 EOR (LS-CO 2 EOR). This  are firstly summarized to help the understanding of
                                                          LS-CO 2 EOR. The detailed description of CO 2 flood
            chapter reviews the studies of CO 2 EOR, mainly CO 2
            water-alternating gas and carbonated water injection,  will be found in the references (Jarrell et al., 2002;
            to investigate the effect of salinity on the mechanisms  Stalkup, 1983).
            of CO 2 EOR process. Laboratory and numerical simula-
            tion studies of LS-CO 2 EOR are discussed to evaluate  MINIMUM MISCIBLE PRESSURE
            whether the additional displacement efficiency employ-
            ing the mechanism of low-salinity waterflood or other  Although there are other solvents, the CO 2 is a good
            effects can be introduced.                    solvent for miscible process. The CO 2 generally forms
                                                          a phase, which has comparable density of a liquid
                                                          and low viscosity, in a high pressure condition. More
            The understanding of CO 2 EOR has been investigated,  importantly, the CO 2 relatively has a low minimum
            and some researchers have reported the experimental  miscible pressure (MMP), which is defined as mini-
            works of carbonated water recovery as early as 1951  mum pressure to achieve a miscibility, compared with
            (Martin, 1951). The first patent of CO 2 EOR technology  the methane and nitrogen. The miscible process can
            was granted by the Atlantic Refinery Company in 1952  be effective for a reservoir system, which has a higher
            (Whorton, Brownscombe, & Dyes, 1952). In 1964, the  pressure than MMP. Because the CO 2 generally results
            field test of CO 2 EOR was developed in the Mead  in a lower MMP compared with the other solvents,
            Strawn Field and the test was designed with carbonated  the CO 2 injection can be used to enhance the miscible
            water injection following CO 2 slug (Holm, apos, &  oil recovery process in a wide range of oil reservoirs.
            Brien, 1971; Holm, 1987). The CO 2 EOR produces
            more oil by 53%e82% over the best performance of
            waterflood. Following the success of pilot test, the first  MISCIBLE/IMMISCIBLE PROCESSES
            commercial CO 2 EOR project was deployed in SACROC  The solvent EOR process can be either a miscible or an
            (Scurry Area Canyon Reef Operators Committee) Unit  immiscible displacement depending on the miscibility
            of the Kelly-Snyder Field in Scurry County, West Texas  condition. The miscibility between two fluids, i.e.,
            (Langston, Hoadley, & Young, 1988). The successful  displacing and displaced fluids, can be achieved by
            field project leads to a number of applications of  first-contact miscibility or multiple-contact miscibility.

            Hybrid Enhanced Oil Recovery using Smart Waterflooding. https://doi.org/10.1016/B978-0-12-816776-2.00005-2
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