Page 68 - A Practical Introduction to Optical Mineralogy
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SILICATE  MINERALS                                                        CHLORITE
               *INTERFERENCE  The colour of the minerals and their strong dispersion make interference   Chlorite                         Phyllosilicate
                    FIGURE   figures difficult to obtain, and these are usually indistinct with optic signs                                  monoclinic
                         and size  of 2V impossible to judge.                               c hh1  ltc  (Mg,Al,Fe) 1z(Si,Al) 80zo(OH)I6
                                                                                                                                     0.57: 1: 1.31, f3  =  97°
                 *EXTINCTION  Oblique with both minerals having variable extinction angles; a ' cleav-
                         age varies from  oo to 50° but this is  also difficult  to  obtain.
                  TWINNING  Simple or repeated on  { 100}.
                OCCURRENCE  Both minerals occur as constituents in  alkali  plutonic rocks (soda-rich
                         rocks),  such  as  nepheline- and  quartz-syenites,  where  they  occur  in
                         association with aegirine or aegirine-augite and apatite. The minerals
                         are late crystallisation  products.
                                                                                                                                     - ----b = (3
                Aenigmatite  Aenigmatite (Na 2 Fe;+TiSi 6 0 20 )  is a mineral closely resembling the alkali
                         amphiboles.  It  has  very  high  relief  (  - 1.8)  and  a  small  positive  2V.
                         Aenigmatite is pleochroic with a red brown, f3 brown, andy dark brown.
                         It is similar to the dark brown amphiboles but has higher Rls. Aenigma-
                         tite often occurs as small phenocrysts in alkaline volcanic rocks such as
                         phonolites.

                                                                                                   II .,  =  1.57-1.66
                         Beryl                                   Cyclosilicate                     11 11  =  1.57-1.67
                                                                                                   11 ,  =  1.57-1.67
                                                                    hexagonal
                                                                   cia 0.9956                      6  =  0.0-0.01
                                                                                                   2V = 20°-60°  +ve or - ve
                              1.560-1.602
                         n 0                                                                         AP is parallel to (010)
                         n.   1.557-1.599                                                          [)  = 2.6-3.3   H  = 2-3
                         a   o.oo3-0.009
                                                                                             1 IIIIIIIK   olourless or green.
                         Uniaxial  +ve (a  prism section  is  length slow)
                                                                                           It  11  11"111  M   reen varieties have a  pale green to colourless, f3  andy darker green.
                         D = 2.66-2.92   H  = 71/2-8
                                                                                               11  ''"  Tabular crystals  with a  pseudo-hexagonal shape.
                   coLouR  Colourless, pale yellow or pale green.                           lll  I'  t11   Perfect { 001}  basal cleavage.
                PLEOCHROISM  Weakly pleochroic in  pale greens if section is  thick.          111  1 11  1   w to  moderate.
                    *HABIT  Hexagonal prism with large basal face.                          1 11"  II IIN   xidation  of iron in  chlorite may occur (the sign changes from  +veto
                  CLEAVAGE  Imperfect basal {0001}.                                                  ve).
                    RELIEF  Low to moderate.                                               1 1  INIII  Nl  1  Very weak, usually  with  anomalous deep Berlin  blue  colour.
                 ALTERATION  Beryl  easily  undergoes  hydrothermal  alteration  to  clay  minerals,  as   .,, Ml Nl  1  Biaxial Bxa figure  on  basal section with small 2V. Usually positive but
                         follows,  the reaction  releasing quartz and phenakite:              '""'K 1   some varieties- chamosite in particular- are optically negative. Inter-
                                                                                                   fe rence  figures  are rarely obtained.
                                                                                             liN I  II liN  Straight to cleavage but can be oblique with small angle y or a ' cl (fast or
                           2Be,Al 2 Si 6 0 18 +  4H 2 ~ Al.Si 40 10 (0H) 8 +  5Si0 2  +  2Be 2Si0 4
                                                kaolin           phenakite                         slow  to  cleavage) ; very small angle(<  5°)  on (010) section.
                                                                                            ,  INN INII  1\s in  micas:  rare.
               BIREFRINGENCE  LOW  first  order greys.                                     ,   1'0 1 Ni l   'hlorite is a  widely  distributed primary mineral in  low grade regional
                  TWINNING  Rare                                                                   111  tamorphic rocks (greenschists), eventually changing to biotite with
                *occuRRENCE  Beryl  occurs  in  vugs  in  granites  and  particularly  in  pegmatites, often   increasing grade; muscovite is also involved in the reaction. The initial
                         associated  with  cassiterite.  The  precious  stone  variety,  aquamarine,   material is usually argillaceous sediments, but basic igneous rocks and
                         occurs in similar locations, but emerald is usually found in metamorphic   tuffs will  give chlorite during regional metamorphism. In some alkali-
                         biotite schists.                                                          ' i ·h rocks, chlorite will break down with increasing P and T and help to

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